Carbon (sp3) tetrel bonding mediated BODIPY supramolecular assembly via unprecedented synergy of Csp3•••N and Csp3•••F pair interactions

被引：13

作者：

Ayhan, Mehmet Menaf ^{[1
]}

Ozcan, Emrah ^{[1
,2
]}

Dedeoglu, Burcu ^{[1
]}

Chumakov, Yurii ^{[3
,4
]}

Zorlu, Yunus ^{[1
]}

Cosut, Bunyemin ^{[1
]}

机构：

[1] Gebze Tech Univ, Dept Chem, Kocaeli, Turkey

[2] Univ South Bohemia, Fac Sci, Inst Phys, Branisovska 1760, Ceske Budejovice 37005, Czech Republic

[3] Gebze Tech Univ, Dept Phys, Kocaeli, Turkey

[4] Inst Appl Phys, MD-2028 Kishinev, Moldova

来源：

CRYSTENGCOMM | 2021年 / 23卷 / 02期

关键词：

ADAPTED PERTURBATION-THEORY; HALOGEN; COOPERATIVITY; HYDROGEN; SIGMA;

D O I：

10.1039/d0ce01640c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Here, we present the first example of sp(3) hybridized carbon centered (C-sp3) tetrel bonding mediated 3D BODIPY assembly via the exceptional synergy of C-sp3 center dot center dot center dot N and C-sp3 center dot center dot center dot F pair interactions. The carbon tetrel bond interaction energies of C-sp3 center dot center dot center dot N and C-sp3 center dot center dot center dot F are amplified significantly as the size of the 1D chain grows from dimer to tetramer BODIPY units.

引用

页码：268 / 272

页数：5

共 56 条

[1] Weak Interactions Get Strong: Synergy between Tetrel and Alkaline-Earth Bonds [J].