Porphyrinic metal-organic frameworks from custom-designed porphyrins

被引:122
作者
Huh, Seong [1 ,2 ]
Kim, Sung-Jin [3 ]
Kim, Youngmee [3 ]
机构
[1] Hankuk Univ Foreign Studies, Dept Chem, Yongin 17035, South Korea
[2] Hankuk Univ Foreign Studies, Prot Res Ctr Bioind, Yongin 17035, South Korea
[3] Ewha Womans Univ, Dept Chem & Nano Sci, Seoul 03760, South Korea
基金
新加坡国家研究基金会;
关键词
SUPRAMOLECULAR CRYSTAL-CHEMISTRY; STATE COORDINATION CHEMISTRY; MN-III-PORPHYRIN; HIGHLY EFFICIENT; ENERGY-TRANSFER; METALLOPORPHYRIN FRAMEWORK; BUILDING-BLOCK; METALLOSUPRAMOLECULAR ARRAYS; ASSEMBLY MODES; OPEN NETWORKS;
D O I
10.1039/c5ce02106e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This paper highlights porphyrinic metal-organic frameworks (porph-MOFs) assembled from metal ions and custom-designed porphyrins. The contents are divided into three sections based on the types of polytopic porphyrin bridging ligands in porph-MOFs: (1) porph-MOFs containing 5,10,15,20-tetra(4-pyridyl)porphyrinato (TPyP) ligand and other pyridyl-based porphyrin bridging ligands, (2) porph-MOFs containing 5,10,15,20-tetrakis(4-carboxyphenyl)porphyrinato (TCPP) ligand and other carboxyphenyl-based porphyrin bridging ligands, and (3) porph-MOFs containing other custom-designed porphyrin-based bridging ligands.
引用
收藏
页码:345 / 368
页数:24
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