Supporting of coupled silver halides onto clinoptilolite nanoparticles as simple method for increasing their photocatalytic activity in heterogeneous photodegradation of mixture of 4-methoxy aniline and 4-chloro-3-nitro aniline

被引:93
作者
Jafari, Sajad [1 ,2 ]
Nezamzadeh-Ejhieh, Alireza [1 ,2 ,3 ]
机构
[1] Islamic Azad Univ, Shahreza Branch, Dept Chem, POB 311-86145, Shahreza, Isfahan, Iran
[2] Islamic Azad Univ, Shahreza Branch, Young Researchers & Elite Club, Shahreza, Iran
[3] Islamic Azad Univ, Shahreza Branch, RCRC, Esfahan, Iran
关键词
Photocatalysis; Nanoparticles; Clinoptilolite; Aniline derivates; Silver halides; HIGHLY EFFICIENT; DEGRADATION; COMPOSITE; ZEOLITE; AG; NANOCOMPOSITE; SURFACES; CATALYST; REMOVAL; COPPER;
D O I
10.1016/j.jcis.2016.11.087
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Novel photocatalyts were synthesized by dispersion of AgX (X = I, Br, Cl) in nano clinoptilolite particles (NCP). The obtained composites (AgX-NCP) were used for the photodegrading of aqueous mixture of 4methoxy aniline and 4-chloro-3-nitroaniline under Hg lamp irradiation. All samples were characterized by FT-IR, XRD, DRS and TEM. The effects of operational parameters such as: the loaded extent of AgX, the amount of photocatalyst, initial pH and concentration on photo mineralization were studied. The degradation extent was monitored by UV-Vis spectroscopy and the results were confirmed by the chemical oxygen demand (COD). (C) 2016 Elsevier Inc. All rights reserved.
引用
收藏
页码:478 / 487
页数:10
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