Crystal structure and Hirshfeld surface analysis of (E)-1-(4-chlorophenyl)-2-[2,2-dichloro-1-(4-fluorophenyl)ethenyl] diazene

被引：21

作者：

Shikhaliyev, Namiq Q. ^{[1
]}

Celikesir, Sevim Turktekin ^{[2
]}

Akkurt, Mehmet ^{[2
]}

Bagirova, Khanim N. ^{[1
]}

Suleymanova, Gulnar T. ^{[1
]}

Toze, Flavien A. A. ^{[3
]}

机构：

[1] Baku State Univ, Organ Chem Dept, Z Xalilov Str 23, AZ-1148 Baku, Azerbaijan

[2] Erciyes Univ, Dept Phys, Fac Sci, TR-38039 Kayseri, Turkey

[3] Univ Douala, Fac Sci, Dept Chem, POB 24157, Douala, Cameroon

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2019年 / 75卷

关键词：

crystal structure; 4-chlorophenyl; 4-fluorophenyl; face-to-face pi-pi stacking interaction; Hirshfeld surface analysis; INTERMOLECULAR INTERACTIONS; QUANTITATIVE-ANALYSIS; HYDROGEN-BONDS; HALOGEN;

D O I：

10.1107/S2056989019003657

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, C14H8Cl3FN2, the planes of the 4-fluorophenyl ring and the 4-chlorophenyl ring make a dihedral angle of 56.13 (13)degrees. In the crystal, molecules are stacked in a column along the a axis via a weak C-H center dot center dot center dot Cl hydrogen bond and face-to-face pi-pi stacking interactions [centroid-centroid distances = 3.8615 (18) and 3.8619 (18) angstrom]. The crystal packing is further stabilized by short Cl center dot center dot center dot Cl contacts. The Hirshfeld surface analysis of the crystal structure indicates that the most important contributions for the crystal packing are from Cl center dot center dot center dot H/H center dot center dot center dot Cl (31.2%), H center dot center dot center dot H (14.8%), C center dot center dot center dot H/H center dot center dot center dot C (14.0%), F center dot center dot center dot H/H center dot center dot center dot F (12.8%), C center dot center dot center dot C (9.0%) and Cl center dot center dot center dot Cl (6.7%) interactions.

引用

页码：465 / +

页数：9

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