Highly active and reusable copper phthalocyanine derivatives catalyzed the hydroxylation of (hetero)aryl halides

被引：4

作者：

Peng, Dao ^{[1
]}

Zhang, Yu ^{[1
]}

Liu, Xiao-Qing ^{[1
]}

Shang, Hang ^{[1
]}

Lin, Gang ^{[1
]}

Jin, Hong-Ying ^{[1
]}

Liu, Xue-Fen ^{[2
]}

He, Ran

Shang, Ye-Han ^{[1
]}

Xu, Yin-Hua ^{[1
]}

Luo, Shu-Ping ^{[1
]}

机构：

[1] Zhejiang Univ Technol, State Key Lab Breeding Base Green Chem Synth Techn, Hangzhou 310014, Peoples R China

[2] Hangzhou Normal Univ, Qianjiang Coll, Hangzhou 310006, Peoples R China

来源：

MOLECULAR CATALYSIS | 2022年 / 525卷

基金：

中国国家自然科学基金;

关键词：

(Hetero)aryl halides; Hydroxylation; Cu-based catalyst; Small molecule catalysis; ARYL HALIDES; EFFICIENT SYNTHESIS; BENZOFURAN DERIVATIVES; SUBSTITUTED PHENOLS; WATER; HYDROXIDE; IODIDES; ETHERS; LIGAND; ACID;

D O I：

10.1016/j.mcat.2022.112342

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We have researched and developed a series of copper phthalocyanine derivatives as new highly active and reusable catalysts for the hydroxylation of (hetero)aryl halides. The perfluorinated copper phthalocyanine (CuPcF16) showed the highest activity for the hydroxylation of aryl iodide with an excellent yield (up to 98%) under low catalytic loading (0.5 mol% CuPcF16). Similarly, the hydroxylation of aryl bromides and aryl chlorides catalyzed by CuPcF16 also had high activity with 42~98% yield. Moreover, the recyclability of this catalyst can up to 6 times without significant loss in catalytic activity.

引用

页数：6

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