Synthesis of copolymeric hydrogels using gamma radiation and their utilization in the removal of some dyes in wastwater

Copolymer hydrogels were prepared by gamma-radiation copolymerization of maleic acid (MA) and 2-hydroxyethylacrylate (HEA) or acrylamide (AAm). The effect of AAm/MA and HEA/MA composition and irradiation dose on the gel fraction yield in the prepared hydrogels was determined. It was found that as the content of MA increased, the gel fraction yield decreased. The increase of irradiation dose resulted in increasing the crosslinked network structure and consequently the gel percent. The parameters of equilibrium swelling, maximum swelling, initial swelling rate, diffusion exponent, and diffusion coefficient of the hydrogels were calculated and evaluated, and it was found that water diffusion to the hydrogels generally was a non-Fickian diffusion type. Characterization of the prepared hydrogels was studied and accordingly the possibility of its practical use in the treatment of waste dyes from aqueous solution was studied. The effect of treatment time, the pH of the feed solution, initial feed concentration, and temperature on the dye uptake was also investigated. The maximum uptake of the investigated dyes was higher for HEA/MA hydrogel than that for AAm/MA hydrogel. (c) 2006 Wiley Periodicals, Inc.