Colloid and nanodimensional catalysts in organic synthesis: VI. Hydrogenation and hydrogenolysis of carbonyl compounds

被引：6

作者：

Mokhov, V. M. ^{[1
]}

Popov, Yu. V. ^{[1
]}

Nebykov, D. N. ^{[1
]}

机构：

[1] Volgograd State Tech Univ, Volgograd 400131, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2014年 / 84卷 / 09期

关键词：

catalysis; nickel nanoparticles; hydrogenation; carbonyl bond; hydrogenolysis; ASYMMETRIC TRANSFER HYDROGENATION; PHASE HYDROGENATION; NANOPARTICLES; KETONES; EFFICIENT; SYSTEM;

D O I：

10.1134/S1070363214090023

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Aldehydes and ketones are found to be hydrogenated to alcohols with hydrogen at atmospheric pressure under the catalysis with nickel nanoparticles. The reaction under study may be used as technologically available and cheap method for hydrogenation of carbonyl groups. It is found that in the case of aromatic ketones hydrogenolysis of C=O bond with partial hydrogenation of aromatic groups takes place.

引用

收藏

页码：1656 / 1661

页数：6

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