Electrical and environmental aging of silicone rubber used in outdoor insulation

被引：157
作者：
Yoshimura, N [1 ]
Kumagai, S
Nishimura, S
机构：
[1] Akita Univ, Dept Elect & Elect Engn, Akita 010, Japan
[2] Yokohama Natl Univ, Dept Elect & Informat Engn, Yokohama, Kanagawa, Japan
来源：
IEEE TRANSACTIONS ON DIELECTRICS AND ELECTRICAL INSULATION | 1999年 / 6卷 / 05期
关键词：
D O I：
10.1109/94.798120
中图分类号：
TM [电工技术]; TN [电子技术、通信技术];
学科分类号：
0808 ; 0809 ;
摘要：
This is a laboratory study on the aging of SIR and hydrophobicity recovery. UV radiation, corona discharges, acid rain, dry-band arcing are employed as sources of the aging. Chemical and morphological analysis is used to detect the surface chemical and structural changes derived from these stresses, The nature of highly mobile low molecular weight (LMW) chains achieving a quick recovery of the hydrophobicity is carefully examined. Their generation and extinction caused by these stresses are investigated. From this study, it is shown that oxidation that induces crosslinking, branching, interchanging and a formation of silanol groups are the most dominant chemical reactions during the aging of SIR. Furthermore, silanol groups that are byproducts of oxidation restrict the diffusion of mobile LMW chains, which decreases the recovery speed of hydrophobicity and accelerates the aging. A typical aging scenario of SIR from the installation to the end of their life is drawn.
引用
收藏
页码：632 / 650
页数：19
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