Synthesis, Transport, and Ionophore Properties of α,ω-Biphosphorylated Azapodands: VIII. Solvent Extraction of the Metal Ions with N,N′-Bis(dioctylphosphorylmethyl)-1,8-diamino-3,6-dioxaoctane

被引:3
|
作者
Garifzyanov, A. R. [1 ]
Leont'ev, S. V. [1 ]
Davletshina, N. V. [1 ]
Voloshin, A. V. [1 ]
Cherkasov, R. A. [1 ]
机构
[1] Kazan Fed Univ, Kazan 420008, Tatarstan, Russia
基金
俄罗斯基础研究基金会;
关键词
SUPPORTED LIQUID-MEMBRANE; ALPHA; OMEGA-DIPHOSPHORYLATED AZA PODANDS; SEPARATION; SCANDIUM; OMEGA-DIAMINES; ACID;
D O I
10.1134/S1070363213110054
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Liquid extraction from the aqueous solutions of perchloric acid with neutral azapodand extractant N,N'-bis(dioctylphosphorylmethyl)-1,8-diamino-3,6-dioxaoctane has been highly efficient in the cases of uranyl ions and some metals of groups II and III. To estimate the synergic effect of organophosphorus extractants, the neutral extractant was applied in the mixture with an acidic component, bis(pentadecyl) phosphoric acid. The synergic effect has exclusively been observed in the extraction of zinc and cadmium ions.
引用
收藏
页码:1997 / 2004
页数:8
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