Synthesis of functionalized mono-, di-, tri-, and tetraphosphines: Attempted application to prepare hyperbranched polymers and dendrimers built with phosphines at each branching point

被引：0

作者：

Huc, V ^{[1
]}

Balueva, A ^{[1
]}

Sebastian, RM ^{[1
]}

Caminade, AM ^{[1
]}

Majoral, JP ^{[1
]}

机构：

[1] CNRS, Chim Coordinat Lab, F-31077 Toulouse 4, France

来源：

SYNTHESIS-STUTTGART | 2000年 / 05期

关键词：

dendrimers; hyperbranched polymer; phosphorus; phosphine; alkynes; Grignard reagents;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of several functionalized mono-, di-, tri-, and tetraphosphines is described. These compounds are used for the attempted preparation of hyperbranched polymers and dendrimers possessing free phosphino groups at each branching point within the structure. Theses attempts were not fully successful, but several phosphaacetylenic derivatives have been isolated.

引用

页码：726 / 730

页数：5

共 28 条

[1] Synthesis and reactivity of σ-alkynyl/P-bonded phosphinoalkyne platinum complexes toward cis-[M(C6F5)2(thf)2] (M = Pt, Pd) [J].