Crystal Structure of [N-(9-Anthracenylmethyl)-1,3-propanediamine]-(2,2′-bipyridine)platinum(II) Chloride

被引：0
|
作者：
Kiwada, Tatsuto [1 ]
Takayama, Hiroshi [2 ]
Katakasu, Hiromu [3 ]
Odani, Akira [1 ]
机构：
[1] Kanazawa Univ, Fac Pharm, Inst Med Pharmaceut & Hlth Sci, Kakuma Machi, Kanazawa, Ishikawa 9201192, Japan
[2] Nagoya Univ, Grad Sch Sci, Dept Chem, Chikusa Ku, Nagoya, Aichi 4648602, Japan
[3] Kanazawa Univ, Sch Pharmaceut Sci, Coll Med Pharmaceut & Hlth Sci, Kakuma Machi, Kanazawa, Ishikawa 9201192, Japan
来源：
X-RAY STRUCTURE ANALYSIS ONLINE | 2019年 / 35卷
关键词：
STACKING; DEPENDENCE; COMPLEXES;
D O I：
10.2116/xraystruct.35.39
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The crystal structure of [N-(9-anthracenylmethyl)-1,3-propanediamine](2,2'-bipyridine)platinum(II) chloride was determined by X-ray crystallography. The title complex crystallized in the monoclinic space group P21/c and Z = 4 with cell parameters a = 11.2466(7)angstrom, b = 17.3553(10)angstrom, c = 13.7027(9)angstrom, beta = 100.501(2)degrees , V = 2629.8(3)angstrom(3). The R-1 [I > 2 sigma (I)] and wR(2) (all data) values are 0.0271 and 0.0619, respectively, for all 5995 independent reflections. The intramolecular pi-pi stacking interaction was observed between the anthracene and the bipyridine. In the crystal packing structure, the intermolecular pi-pi stacking interaction was observed.
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页码：39 / 41
页数：3
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