Crystal Structure of [N-(9-Anthracenylmethyl)-1,3-propanediamine]-(2,2′-bipyridine)platinum(II) Chloride

被引：0

作者：

Kiwada, Tatsuto ^{[1
]}

Takayama, Hiroshi ^{[2
]}

Katakasu, Hiromu ^{[3
]}

Odani, Akira ^{[1
]}

机构：

[1] Kanazawa Univ, Fac Pharm, Inst Med Pharmaceut & Hlth Sci, Kakuma Machi, Kanazawa, Ishikawa 9201192, Japan

[2] Nagoya Univ, Grad Sch Sci, Dept Chem, Chikusa Ku, Nagoya, Aichi 4648602, Japan

[3] Kanazawa Univ, Sch Pharmaceut Sci, Coll Med Pharmaceut & Hlth Sci, Kakuma Machi, Kanazawa, Ishikawa 9201192, Japan

来源：

X-RAY STRUCTURE ANALYSIS ONLINE | 2019年 / 35卷

关键词：

STACKING; DEPENDENCE; COMPLEXES;

D O I：

10.2116/xraystruct.35.39

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The crystal structure of [N-(9-anthracenylmethyl)-1,3-propanediamine](2,2'-bipyridine)platinum(II) chloride was determined by X-ray crystallography. The title complex crystallized in the monoclinic space group P21/c and Z = 4 with cell parameters a = 11.2466(7)angstrom, b = 17.3553(10)angstrom, c = 13.7027(9)angstrom, beta = 100.501(2)degrees , V = 2629.8(3)angstrom(3). The R-1 [I > 2 sigma (I)] and wR(2) (all data) values are 0.0271 and 0.0619, respectively, for all 5995 independent reflections. The intramolecular pi-pi stacking interaction was observed between the anthracene and the bipyridine. In the crystal packing structure, the intermolecular pi-pi stacking interaction was observed.

引用

页码：39 / 41

页数：3

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