Crystal structure and magnetic property of heteronuclear copper-lanthanum carboxylate complex

被引：0

作者：

Wu, B ^{[1
]}

Lu, WM ^{[1
]}

Zheng, XM ^{[1
]}

机构：

[1] Zhejiang Univ, Inst Catalysis, Hangzhou 310028, Zhejiang, Peoples R China

来源：

CHINESE JOURNAL OF CHEMISTRY | 2002年 / 20卷 / 09期

关键词：

copper; lanthanum; heteronuclear; crystal structure; magnetic property;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title Complex, [CuLaL5 (phen) (C2H5OH)](2) (where L = alpha-methylacrylato; Phen = 1, 10-phenanthroline), has been Prepared and Its structure has been determined by X-ray diffraction analysis. The complex crystallizes in triclinic system with space group P (1) over bar. Crystal data: a = 1.2725 (3) nm, b = 1.4421(4) nm, c = 1.2109(2) nm, alpha = 109.48(2)degrees, beta = 115.26(2)degrees, gamma = 66.42(2)degrees. The complex is a discrete tetranuclear CuLaLaCa molecule bridged by alpha-methylacrylato groups. Magnetic property of the complex was also measured and discussed.

引用

页码：846 / 850

页数：5

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