Cu2O-loaded TiO2 heterojunction composites for enhanced photocatalytic H2 production

被引:33
作者
Chen, Jun-Li [1 ]
Liu, Ming-Ming [1 ]
Xie, Shi-Yu [1 ]
Yue, Li-Juan [1 ]
Gong, Fei-Long [1 ]
Chai, Kai-Ming [1 ]
Zhang, Yong-Hui [1 ]
机构
[1] Zhengzhou Univ Light Ind, Coll Mat & Chem Engn, Collaborat Innovat Ctr Environm Pollut Control &, Zhengzhou 450002, Peoples R China
关键词
Cu2O; TiO2; H(2)production; Heterojunction; Photocatalysis; CU2O; HETEROSTRUCTURE; NANOPARTICLES; EVOLUTION; OXIDATION; SHELLS;
D O I
10.1016/j.molstruc.2021.131294
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The Cu2O/TiO2 heterogeneous materials were fabricated via simple hydrothermal and physical mixing processes to investigate the photocatalytic H-2 production performance. The morphology evolution of Cu2O was systematically explored by adjusting the amount of chemical reagents. The CT-70 (the additive amount of TiO2 was 70 wt%) exhibited superior photocatalytic activity with H-2 production of 8.33 mmol g(-1) in 6 h, which was about 416 and 49-fold more elevated those of Cu2O and TiO2. The enhancement of H-2 generation was ascribed to the proper band gap structure and the heterojunction between Cu2O and TiO2. This work provides a strategy for the simple preparation of composite materials with high photocatalytic activity. (C) 2021 Elsevier B.V. All rights reserved.
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页数:7
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共 46 条
  • [1] Cu2O/TiO2 heterostructures for CO2 reduction through a direct Z-scheme: Protecting Cu2O from photocorrosion
    Aguirre, Matias E.
    Zhou, Ruixin
    Eugene, Alexis J.
    Guzman, Marcelo I.
    Grela, Maria A.
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2017, 217 : 485 - 493
  • [2] Gold nanoparticles-sensitized wide and narrow band gap TiO2 for visible light applications: a comparative study
    Ansari, Sajid Ali
    Khan, Mohammad Mansoob
    Ansari, Mohd Omaish
    Cho, Moo Hwan
    [J]. NEW JOURNAL OF CHEMISTRY, 2015, 39 (06) : 4708 - 4715
  • [3] Light-Induced-Magnetoresistance in p-n Junction Device
    Cao, Yang
    Sui, Wenbo
    Wang, Tao
    Si, Mingsu
    Shi, Huigang
    Yang, Dezheng
    Xue, Desheng
    [J]. IEEE ELECTRON DEVICE LETTERS, 2020, 41 (03) : 509 - 512
  • [4] Morphology control of mesoporous Cu2O by reductants and its photocatalytic activity
    Chu, Xiao-Zhong
    Cheng, Zhi-Peng
    Zhao, Yi-Jiang
    Xu, Ji-Ming
    Li, Mei-Sheng
    Hu, Lei
    Zhou, Shou-Yong
    Wu, Fei-Yue
    Lee, Chang-Ha
    [J]. CERAMICS INTERNATIONAL, 2017, 43 (11) : 8222 - 8229
  • [5] Photocatalytic performance of TiO2 thin film decorated with Cu2O nanoparticles by laser ablation
    Deng, Cao
    Hong, Ruijin
    Jing, Ming
    Shi, Jingqi
    Yan, Tingzhen
    Tao, Chunxian
    Zhang, Dawei
    [J]. OPTICAL MATERIALS, 2019, 94 : 130 - 137
  • [6] A facile method for preparing Pt/TiO2 photocatalyst with enhanced activity using dielectric barrier discharge
    Di, Lanbo
    Xu, Zhijian
    Wang, Kai
    Zhang, Xiuling
    [J]. CATALYSIS TODAY, 2013, 211 : 109 - 113
  • [7] A novel metal-free photocatalyst polyphenylene sulfide: Synthesis, characterization and performance evaluation
    Fan, You
    Ben, Haijie
    Li, Longfeng
    Meng, Sugang
    Zhang, Sujuan
    Zheng, Xiuzhen
    Zhang, Jinfeng
    Yin, Lichang
    Chen, Shifu
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2020, 274
  • [8] Facile synthesis of hollow Cu2O octahedral and spherical nanocrystals and their morphology-dependent photocatalytic properties
    Feng, Lili
    Zhang, Chunlei
    Gao, Guo
    Cui, Daxiang
    [J]. NANOSCALE RESEARCH LETTERS, 2012, 7
  • [9] TiO2/rGO/Cu2O ternary hybrid for high-performance photoelectrochemical applications
    Hajialilou, E.
    Asgharzadeh, H.
    Asl, Sh. Khameneh
    [J]. APPLIED SURFACE SCIENCE, 2021, 544 (544)
  • [10] The study on preparation and photocatalytic activities of Cu2O/TiO2 nanoparticles
    Han, Tiehu
    Zhou, Dongmei
    Wang, Huigang
    Zheng, Xuming
    [J]. JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, 2015, 3 (04): : 2453 - 2462