3D nickel(II) and cobalt(II) complexes based on 1,4-bis(1,2,4-triazol-1-yl) butane (btb) and PF6- synthons

被引：2

作者：

Wang, Kai ^{[1
]}

Qi, Xiao-Yu ^{[1
]}

Wang, Qing-Lun ^{[1
]}

Ren, Hong-Xia ^{[2
]}

Ma, Yue ^{[1
]}

Cheng, Peng ^{[1
]}

Liao, Dai-Zheng ^{[1
]}

机构：

[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China

[2] Nankai Univ, Minist Educ, Key Lab Adv Energy Mat Chem, Tianjin 300071, Peoples R China

来源：

INORGANICA CHIMICA ACTA | 2016年 / 441卷

基金：

中国国家自然科学基金;

关键词：

Coordination polymer; Bis(triazole) ligands; Crystal structure; Magnetic properties; METAL-ORGANIC FRAMEWORKS; MANGANESE COORDINATION POLYMERS; FLEXIBLE BIS(TRIAZOLE); CRYSTAL-STRUCTURES; MAGNETIC-PROPERTIES; ANION-EXCHANGE; LIGAND; SERIES; LUMINESCENT; COPPER(II);

D O I：

10.1016/j.ica.2015.11.014

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The diffusion reaction of 1,4-bis(1,2,4-triazol-1-yl) butane (btb) with Co(II)/Ni(II) ions as well as counter anions (PF6) yielded two new coordination polymers, [Co-1.5(btb)(4.5)](PF6)(3) (1) and [Ni-2(btb)(6)](PF6)(4) (2). Both complexes have 3D uninodal 6-connected (4(12),6(3)) net topology, forming triple interpenetrating structure. The distance between adjacent metal ions via btb bridging ligand is in the range of 13.930-14.181 angstrom and 13.982-14.086 angstrom, respectively. The magnetic behaviors of complexes 1 and 2 have been analyzed by one-ion approximation with spin-orbit coupling and zero-field splitting, respectively. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：131 / 136

页数：6

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