Application of in situ titanite U-Pb geochronology to volcanic-hosted magnetite deposit: New constraints on the timing and genesis of the Zhibo deposit, Western Tianshan, NW China

The Awulale metallogenic belt within the Western Tianshan orogenic belt of northwestern China includes four large iron oxide deposits with a total resource of similar to 1000 million metric tons (Mt) Fe. Among these, the Zhibo deposit is a large (337 Mt at 26-68 wt% Fe) volcanic-hosted magnetite deposit, where massive Ti-poor magnetite ores are hosted in the Carboniferous volcanic and volcaniclastic sequences. Here we use in situ U-Pb analyses of titanite and zircon by laser ablation ICP-MS to place tight constraints on the timing and genesis of iron mineralization at Zhibo. Titanite in the magnetite ore are closely associated with magnetite and Ca alteration assemblages consisting of actinolite, epidote, and calcite. The dated titanite exhibit strongly fractionated REE patterns with heavy REE enrichment, neutral to negative Eu anomalies, and have low Th and U concentrations, and low Th/U ratios. The textural and geochemical characteristics indicate that the titanite are hydrothermal in origin and coeval with magnetite in the paragenetic sequence. Titanite from three magnetite ores yield weighted mean Pb-207-corrected Pb-206/U-238 ages of 310.3 +/- 1.8 Ma (MSWD = 0.17), 310.1 +/- 1.8 Ma (MSWD = 0.30), and 315.3 +/- 2.5 Ma (MSWD = 0.26), constraining the iron mineralization at Zhibo to a time interval between 315 Ma and 310 Ma. Magmatic zircon from a host andesite sample yield U-Pb age of 316.3 +/- 3.4 Ma (MSWD = 0.079). The overlapping ages for magnetite ores and the host volcanic rocks confirm a genetic relationship between them, and are consistent with a magmatic contribution to the mineralization system, as also indicated by Fe and O isotope data of magnetite in previous work. These new U-Pb results are also consistent with age estimates for mineralization and igneous activity in other major magnetite deposits in the Awulale iron metallogenic belt, indicating a significant iron mineralization event related to the ca. 315-300 Ma volcanism. Combined with previous geological and geochemical evidence, we conclude that the Zhibo magnetite deposit was formed mainly by iron-rich fluids derived from a mafic to intermediate magma in a volcano-plutonic structure.