(Carbonato-κ2O,O′)bis-(1,10-phenanthroline-κ2N,N′)cobalt(III) chloride pentahydrate

被引：20

作者：

Fu, XC

Wang, XY

Li, MT

Wang, CG ^{[1
]}

Deng, XT

机构：

[1] Cent China Normal Univ, Dept Chem, Wuhan 430079, Hubei, Peoples R China

[2] W Anhui Uiv, Dept Biol Chem, Luan 237000, Anhui, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2006年 / 62卷

关键词：

D O I：

10.1107/S1600536806015558

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [Co(CO3)(C12H8N2)(2)]Cl.5H(2)O, contains [Co(CO3)(phen)(2)](+) cations (phen = 1,10-phenanthroline), chloride ions and five independent non-coordinated water molecules, four of which show positional disorder. The Co-III atom displays a distorted octa-hedral geometry, being coordinated by four N atoms of two 1,10-phenanthroline ligands and two O atoms of the bidentate chelating carbonate group. The crystal packing is consolidated by hydrogen bonds and aromatic pi-pi stacking inter-actions between neighboring phenanthroline rings.

引用

页码：M1263 / M1265

页数：3

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