Tuning the Langasite, La3SbZn3Si2O14, towards white light emission: synthesis, structure, SHG and photoluminescence studies

A series of single-phase color-tunable Langasite, La3SbZn3Si2O14:RE3+ (RE = Eu, Tb, and Tm) phosphors have been prepared and characterized employing X-ray diffraction (XRD), Raman, and photoluminescence (PL) studies. The substituted compounds, La3SbZn3Si2O14:Eu3+, La3SbZn3Si2O14:Tb3+ and La3SbZn3Si2O14:Tm3+ exhibit the characteristic emissions of Eu3+ (red), Tb3+ (green) and Tm3+ (blue), respectively. By carefully adjusting the concentration of Eu3+ ions in the La3SbZn3Si2O14:1% Tm3+, 2% Tb3+, x% Eu3+ system, we achieved a white emission with a reasonable quantum yield. The compounds are found to be SHG (second-harmonic generation) active with the highest values of 3.6 x KDP (potassium dihydrogen phosphate). In addition, the compounds exhibit reasonable dielectric constants with low loss. The present study demonstrates the color tunability of the Langasite family of compounds and establishes it as an adaptable structure.