Recent Advances in Metal-Catalyzed, Electrochemical Coupling Reactions of sp2 Halides/Boronic Acids and sp3 Centers

被引：9

作者：

Gale-Day, Zachary J. ^{[1
]}

机构：

[1] Univ Calif San Francisco, Chem & Chem Biol, 675 Nelson Rising Ln, San Francisco, CA 94158 USA

来源：

SYNTHESIS-STUTTGART | 2021年 / 53卷 / 05期

关键词：

electrochemistry; nickel; copper; reduction; cross-coupling; sp(2)-sp(3); ALKYL-HALIDES; ARYL HALIDES; MECHANISTIC ASPECTS; NICKEL CATALYSIS; BROMIDES; REDUCTION; AMINATION; ZINC; DERIVATIVES; STRATEGIES;

D O I：

10.1055/s-0040-1706085

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Traditionally, metal-catalyzed cross-coupling reactions rely on stable but expensive metals, such as palladium. However, the recent development of synthetic organic electrochemistry allows for in situ redox manipulations, expanding the use of cheaper, abundant and sustainable metals, such as nickel and copper as efficient cross-coupling catalysts. This short review covers the recent advances in metal-catalyzed electrochemical coupling reactions, with a focus on reactions of sp(2) electrophiles and nucleophiles with sp(3) coupling partners to form both C-C and C-heteroatom bonds. 1 Introduction 2 Nickel-Catalyzed C-C sp(2)-sp(3) Coupling Reactions 3 Coupling of Aryl Groups with Heteroatomic Nuclei 4 Conclusion

引用

页码：879 / 888

页数：10

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