Activated carbon fibers prepared directly from stabilized fibers for use as electrodes in supercapacitors

被引:34
作者
Diez, Noel [1 ]
Diaz, Patricia [1 ]
Alvarez, Patricia [1 ]
Gonzalez, Zoraida [1 ]
Granda, Marcos [1 ]
Blanco, Clara [1 ]
Santamaria, Ricardo [1 ]
Menendez, Rosa [1 ]
机构
[1] INCAR CSIC, Inst Nacl Carbon, Oviedo 33080, Spain
关键词
Carbon fibers; chemical activation; stabilized fibers; supercapacitors; PERFORMANCE; CAPACITORS; STORAGE; PITCH;
D O I
10.1016/j.matlet.2014.08.017
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A novel type of carbon fibers, obtained by direct chemical activation of stabilized fibers (non-carbonized), is investigated as active electrode material in supercapacitors (SCs). The main advantage of this novel synthetic method is that it avoids the step of carbonization of the stabilized fibers prior to activation, reducing therefore their cost of production. The as-obtained materials exhibit specific capacitances up to 100 F g(-1) in aqueous electrolytes (1.0 M H2SO4), values that are not only higher than those obtained with conventional fibers but also comparable to the capacitances of SCs based on well-established reference materials such as commercial activated carbons (ACs). (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:214 / 217
页数:4
相关论文
共 18 条
[1]   Electrochemical capacitor performance of mesoporous carbons obtained by templating technique [J].
Alvarez, S ;
Blanco-López, MC ;
Miranda-Ordieres, AJ ;
Fuertes, AB ;
Centeno, TA .
CARBON, 2005, 43 (04) :866-870
[2]  
[Anonymous], 1999, ELECTROCHEMICAL SUPE
[3]  
[Anonymous], 2001, ELECTROCHEMICAL METH
[4]  
[Anonymous], FIBRAS CARBON PREPAR
[5]   Adsorption of gases in multimolecular layers [J].
Brunauer, S ;
Emmett, PH ;
Teller, E .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1938, 60 :309-319
[6]   Optimisation of the melt-spinning of anthracene oil-based pitch for isotropic carbon fibre preparation [J].
Diez, Noel ;
Alvarez, Patricia ;
Santamaria, Ricardo ;
Blanco, Clara ;
Menendez, Rosa ;
Granda, Marcos .
FUEL PROCESSING TECHNOLOGY, 2012, 93 (01) :99-104
[7]  
Donnet J.B., 1990, INT FIBER SCI TECHNO
[8]  
Dubinin MM, 1975, RECENT PROGR SURFACE, V9
[9]   Carbon materials for the electrochemical storage of energy in capacitors [J].
Frackowiak, E ;
Béguin, F .
CARBON, 2001, 39 (06) :937-950
[10]  
Kim DY, 2013, APPL CHEM ENG, V24, P587