Oxo-, hydroxo-, and peroxo-bridged Fe(III) phosphonate cages

被引：100

作者：

Konar, Sanjit ^{[1
]}

Bhuvanesh, Nattamai ^{[1
]}

Clearfield, Abraham ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 30期

关键词：

D O I：

10.1021/ja063388s

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of five Fe(III) phosphonate clusters with four different topologies is reported. The choice of coligand carboxylate plays an important role in directing the structure of the molecule. [Fe9(O)4(O2CCMe3)13(C10P)3] (1) and [Fe9(O)2(OH)(CO2Ph)10(C10P)6(H2O)2](CH3CN)7 (2; camphyl phosphonic acid, C10H17PO3H2 = C10PH2) represent two unprecedented nonanuclear Fe(III) cages having Fe9O4 and Fe9(O)2(OH) core structures, respectively. Whereas [Fe6O2(O)2(O2CCMe3)8(C10P)2 (H2O)2](CH3CN)4 (3) is a peroxo-bridged hexameric compound with an Fe6(O)2(O2) core. [Fe4(O)(O2CCMe3)4(C10P)3(Py)4](CH3CN)3 (4) and [Fe4(O)(O2CPh)4(C10P)3(Py)4](Py)3(CH3CN)2 (5; Py = pyridine) represents two tetranuclear clusters with the same Fe4O core structure. Copyright © 2006 American Chemical Society.

引用

页码：9604 / 9605

页数：2

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