Bimetallic catalysis for C-C and C-X coupling reactions

被引:316
作者
Pye, Dominic R. [1 ]
Mankad, Neal P. [1 ]
机构
[1] Univ Illinois, Dept Chem, 845 W Taylor St, Chicago, IL 60607 USA
关键词
COOPERATIVE PALLADIUM/COPPER CATALYSIS; TRANSITION-METAL-COMPLEXES; HETEROATOM BOND FORMATION; RING-OPENING REACTIONS; SCHIFF-BASE COMPLEXES; SYNERGISTIC CATALYSIS; DUAL CATALYSIS; HETEROBIMETALLIC COMPLEXES; EPOXIDE CARBONYLATION; ACETYLENE DERIVATIVES;
D O I
10.1039/c6sc05556g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Bimetallic catalysis represents an alternative paradigm for coupling chemistry that complements the more traditional single-site catalysis approach. In this perspective, recent advances in bimetallic systems for catalytic C-C and C-X coupling reactions are reviewed. Behavior which complements that of established single-site catalysts is highlighted. Two major reaction classes are covered. First, generation of catalytic amounts of organometallic species of e.g. Cu,Au,or Ni capable of transmetallation to a Pd co- catalyst (or other traditional cross-coupling catalyst) has allowed important new C-C coupling technologies to emerge. Second, catalytic transformations involving binuclear bond-breaking and/epresent a frontier area for C-C and C-X coupling processes.
引用
收藏
页码:1705 / 1718
页数:14
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