Bronsted Acid/Organic Photoredox Cooperative Catalysis: Easy Access to Tri- and Tetrasubstituted Alkenylphosphorus Compounds from Alcohols and P-H Species

被引：41

作者：

Xie, Peizhong ^{[1
]}

Fan, Jing ^{[1
]}

Liu, Yanan ^{[1
]}

Wo, Xiangyang ^{[1
]}

Fu, Weishan ^{[1
]}

Loh, Teck-Peng ^{[1
,2
,3
]}

机构：

[1] Nanjing Tech Univ, Inst Adv Synth, Sch Chem & Mol Engn, Jiangsu Natl Synerget Innovat Ctr Adv Mat, Nanjing 211816, Jiangsu, Peoples R China

[2] Nanyang Technol Univ, Sch Phys & Math Sci, Div Chem & Biol Chem, Singapore 637371, Singapore

[3] Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China

来源：

ORGANIC LETTERS | 2018年 / 20卷 / 11期

基金：

中国国家自然科学基金;

关键词：

PHOSPHINE OXIDES; OXIDATIVE ADDITION; DIPHENYLPHOSPHINE OXIDE; SELECTIVE SYNTHESIS; ALPHA-ALKYLATION; TERMINAL ALKYNES; BOND FORMATION; C BOND; HYDROPHOSPHORYLATION; ALKENES;

D O I：

10.1021/acs.orglett.8b01173

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A Bronsted acid/organic photoredox cooperative catalytic system toward P-C bond formation from alcohols and P-H species is developed. With the assistance of visible light and TBHP, the reactions proceeded smoothly in an environmentally benign manner to give various alkenyl-phosphorus compounds in high efficiency.

引用

页码：3341 / 3344

页数：4

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