A sodium-enabled 'Pourbaix sensor': a three-input AND logic gate as a 'lab-on-a-molecule' for monitoring Na+, pH and pE

被引:102
作者
Magri, David C. [1 ]
Fava, Matthew Camilleri [1 ]
Mallia, Carl J. [1 ]
机构
[1] Univ Malta, Dept Chem, MSD 2080, Msida, Malta
关键词
AQUEOUS-SOLUTION; CHEMICAL INPUTS; FLUORESCENT; SYSTEMS; ION; DERIVATIVES; ASSOCIATION; FERROCENE; PROTON; METAL;
D O I
10.1039/c3cc48075e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel supramolecular three-input AND logic gate is demonstrated as a 'lab-on-a-molecule' for monitoring the Na+, pH and pE levels in solution by communicating a fluorescence signal. The fluorescence signal is modulated by three photoinduced electron transfer reactions that are controlled by an unprecedented combination of two cation binding events and one redox reaction.
引用
收藏
页码:1009 / 1011
页数:3
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[1]   Reductive amination of aldehydes and ketones with sodium triacetoxyborohydride. Studies on direct and indirect reductive amination procedures [J].
AbdelMagid, AF ;
Carson, KG ;
Harris, BD ;
Maryanoff, CA ;
Shah, RD .
JOURNAL OF ORGANIC CHEMISTRY, 1996, 61 (11) :3849-3862
[2]   Smart molecules at work-mimicking advanced logic operations [J].
Andreasson, Joakim ;
Pischel, Uwe .
CHEMICAL SOCIETY REVIEWS, 2010, 39 (01) :174-188
[3]  
Ashton PR, 2001, CHEM-EUR J, V7, P3482, DOI 10.1002/1521-3765(20010817)7:16<3482::AID-CHEM3482>3.0.CO
[4]  
2-G
[5]   Electrofluorochromism: from molecular systems to set-up and display [J].
Audebert, P. ;
Miomandre, F. .
CHEMICAL SCIENCE, 2013, 4 (02) :575-584
[6]  
Balzani V., 2008, MOL DEVICES MACHINES, DOI DOI 10.1002/9783527621682
[7]   Processing energy and signals by molecular and supramolecular systems [J].
Balzani, Vincenzo ;
Credi, Alberto ;
Venturi, Margherita .
CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (01) :26-39
[8]   LUMINESCENCE AND CHARGE-TRANSFER .2. AMINOMETHYL ANTHRACENE-DERIVATIVES AS FLUORESCENT PET (PHOTOINDUCED ELECTRON-TRANSFER) SENSORS FOR PROTONS [J].
BISSELL, RA ;
CALLE, E ;
DE SILVA, AP ;
DESILVA, SA ;
GUNARATNE, HQN ;
HABIBJIWAN, JL ;
PEIRIS, SLA ;
RUPASINGHE, RADD ;
SAMARASINGHE, TKSD ;
SANDANAYAKE, KRAS ;
SOUMILLION, JP .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1992, (09) :1559-1564
[9]   Selective Manipulation of ICT and PET Processes in Styryl-Bodipy Derivatives: Applications in Molecular Logic and Fluorescence Sensing of Metal Ions [J].
Bozdemir, O. Altan ;
Guliyev, Ruslan ;
Buyukcakir, Onur ;
Selcuk, Sencer ;
Kolemen, Safacan ;
Gulseren, Gulcihan ;
Nalbantoglu, Tugrul ;
Boyaci, Hande ;
Akkaya, Engin U. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (23) :8029-8036
[10]  
CAMERON IL, 1980, CANCER RES, V40, P1493