Biomimetic Iron-Catalyzed Asymmetric Epoxidations: Fundamental Concepts, Challenges and Opportunities

被引：60

作者：

Gelalcha, Feyissa Gadissa ^{[1
]}

机构：

[1] Texas A&M Univ Kingsville, Dept Chem, Kingsville, TX 78363 USA

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2014年 / 356卷 / 2-3期

关键词：

asymmetric catalysis; epoxides; green chemistry; iron; oxidation; SOLUBLE METHANE MONOOXYGENASE; O BOND-CLEAVAGE; OLEFIN CIS-DIHYDROXYLATION; AQUEOUS HYDROGEN-PEROXIDE; HIGH-VALENT IRON; COUPLED ELECTRON-TRANSFER; ISOPENICILLIN N-SYNTHASE; C-H HYDROXYLATION; NONHEME IRON; ENANTIOSELECTIVE EPOXIDATION;

D O I：

10.1002/adsc.201300716

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The state-of-the-art in the non-enzymatic iron-catalyzed asymmetric epoxidation of CC double bonds is reviewed within the broader context of biomimetic oxidation catalysis. After introducing fundamental concepts of oxygen activation in nature and by man, historical landmarks, recent breakthroughs, scopes and limitations in relation to existing methodologies and their impact on future directions are assessed, focusing mainly on progress made in the last five years.

引用

页码：261 / 299

页数：39

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