Zinc Chloride-Promoted Coupling Reaction between Calcium Carbide and Aryl Chlorides

被引：12
|
作者：
Jing, Tianna [1 ]
Liu, Ning [1 ]
Xu, Caixia [1 ]
Bu, Qingqing [1 ]
机构：
[1] Shihezi Univ, Key Lab Green Proc Chem Engn Xinjiang Bingtuan, Sch Chem & Chem Engn, North Fourth Rd, Shihezi 832003, Xinjiang, Peoples R China
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2022年 / 2022卷 / 23期
基金：
中国国家自然科学基金;
关键词：
Aryl chlorides; Catalysis; Coupling reaction; Diarylethynes; Palladium; ONE-POT SYNTHESIS; TERMINAL ALKYNES; PALLADIUM; HALIDES; ELECTROPHILES; FLUORIDE; REAGENT;
D O I：
10.1002/ejoc.202200178
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The direct synthesis of diarylethynes from less-reactive aryl chlorides and calcium carbide was accomplished by palladium catalysis. The coupling reaction is provided with broad substrate scope, the use of ZnCl2 as cocatalyst, and the use of safe, inexpensive and easy to handle acetylene source, and provided the desired 1,2-Bis(9-anthryl)acetylene, even when being highly sterically hindered.
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页数：4
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