Long-term ageing behaviour in Ge-Se glasses

被引:31
作者
Golovchak, Roman [1 ]
Kozdras, Andrzej [2 ]
Shpotyuk, Oleh [1 ,3 ]
Kozyukhin, Sergey [4 ]
Saiter, Jean-Marc [5 ]
机构
[1] Lviv Sci Res Inst Mat SRC Carat, UA-79031 Lvov, Ukraine
[2] Opole Univ Technol, Dept Phys, PL-45370 Opole, Poland
[3] Jan Dlugosz Univ, Inst Phys, PL-42201 Czestochowa, Poland
[4] RAS, Inst Gen & Inorgan Chem, Moscow 199991, Russia
[5] Univ Rouen, LECAP, FRE3101, PBS,Fac Sci,Inst Mat Rouen, F-76801 St Etienne, France
关键词
CHALCOGENIDE GLASSES; INTERMEDIATE PHASE; SILICATE-GLASSES; ROOM-TEMPERATURE; GEXSE1-X GLASSES; BINARY; SYSTEM; MODEL;
D O I
10.1007/s10853-009-3540-6
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Effect of long-term physical ageing (similar to 18-21 years) in vitreous germanium selenides is studied using differential scanning calorimetry method. It is compared with short-term physical ageing observed in these glasses earlier. Low compositional limit of the non-ageing ability determined using old samples coincides with the onset of reversibility window obtained using short-term aged samples of Ge-Se system by temperature modulated differential scanning calorimetry technique.
引用
收藏
页码:3962 / 3967
页数:6
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