Two three-dimensional metal-organic frameworks constructed by multiple building blocks of benzenetricarboxylate and bis(imidazole) ligands

被引：17
|
作者：
Liu, Min [1 ]
Yang, Zhipei [1 ]
Sun, Wenhao [1 ]
Li, Xiuping [1 ]
Li, Juan [1 ]
Ma, Jinshi [1 ]
Yang, Guoqiang [1 ]
机构：
[1] Chinese Acad Sci, Beijing Natl Lab Mol Sci, Key Lab Photochem, Inst Chem, Beijing 100080, Peoples R China
来源：
INORGANICA CHIMICA ACTA | 2009年 / 362卷 / 08期
基金：
中国国家自然科学基金;
关键词：
Metal-organic frameworks; Hydrothermal synthesis; Multiple building blocks; Crystal structures; Zinc coordination polymers; COORDINATION POLYMERS; AROMATIC POLYCARBOXYLATE; TRIMESIC ACID; DESIGN; COMPLEXES; POLYROTAXANE; SEPARATION; CLUSTERS; SOLIDS; LAYER;
D O I：
10.1016/j.ica.2009.01.010
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two novel metal-organic frameworks [Zn-3(BTC)(2)(bbi)(3)](n) (1) (H3BTC = 1,3,5-benzenetricarboxylate, bbi = 1,1'-(1,4-butanediyl)bis(imidazole)) and{[Zn-3(BTC)(2)(bix)(3) center dot 2.5H(2)O]}(n) (2) (bix = 1,4-bis(imidazole-1-ylmethyl) benzene) have been hydrothermally prepared and characterized. Analysis of the structure of 1 displays a 3D framework exhibiting a threefold interpenetration net of identical Zn-1.5(BTC)(bbi)(1.5) single frameworks. In the structure of 2, BTC3- and bix build up infinite tubes extending to a 3D non-interpenetrated porous framework. Moderate fluorescent emissions in the solid state at room temperature were observed in both the compounds. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码：2884 / 2889
页数：6
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