Two three-dimensional metal-organic frameworks constructed by multiple building blocks of benzenetricarboxylate and bis(imidazole) ligands

被引：17

作者：

Liu, Min ^{[1
]}

Yang, Zhipei ^{[1
]}

Sun, Wenhao ^{[1
]}

Li, Xiuping ^{[1
]}

Li, Juan ^{[1
]}

Ma, Jinshi ^{[1
]}

Yang, Guoqiang ^{[1
]}

机构：

[1] Chinese Acad Sci, Beijing Natl Lab Mol Sci, Key Lab Photochem, Inst Chem, Beijing 100080, Peoples R China

来源：

INORGANICA CHIMICA ACTA | 2009年 / 362卷 / 08期

基金：

中国国家自然科学基金;

关键词：

Metal-organic frameworks; Hydrothermal synthesis; Multiple building blocks; Crystal structures; Zinc coordination polymers; COORDINATION POLYMERS; AROMATIC POLYCARBOXYLATE; TRIMESIC ACID; DESIGN; COMPLEXES; POLYROTAXANE; SEPARATION; CLUSTERS; SOLIDS; LAYER;

D O I：

10.1016/j.ica.2009.01.010

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two novel metal-organic frameworks [Zn-3(BTC)(2)(bbi)(3)](n) (1) (H3BTC = 1,3,5-benzenetricarboxylate, bbi = 1,1'-(1,4-butanediyl)bis(imidazole)) and{[Zn-3(BTC)(2)(bix)(3) center dot 2.5H(2)O]}(n) (2) (bix = 1,4-bis(imidazole-1-ylmethyl) benzene) have been hydrothermally prepared and characterized. Analysis of the structure of 1 displays a 3D framework exhibiting a threefold interpenetration net of identical Zn-1.5(BTC)(bbi)(1.5) single frameworks. In the structure of 2, BTC3- and bix build up infinite tubes extending to a 3D non-interpenetrated porous framework. Moderate fluorescent emissions in the solid state at room temperature were observed in both the compounds. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：2884 / 2889

页数：6

共 33 条

[1] In(OH)BDC•0.75BDCH2 (BDC = benzenedicarboxylate), a hybrid inorganic-organic vernier structure [J].