Crystal structure and magnetic properties of heterotrinuclear complex, (cutren)(2)Fe(CN)(6)center dot 12H(2)O

被引：16
|
作者：
Zou, JZ
Xu, Z
Huang, XY
Zhang, WL
Shen, XP
Yu, YP
机构：
[1] NANJING UNIV,STATE KEY LAB COORDINAT CHEM,INST COORDINAT CHEM,NANJING 210093,PEOPLES R CHINA
[2] CHINESE ACAD SCI,FUJIAN INST RES STRUCT MATTER,FUZHOU 350002,PEOPLES R CHINA
[3] ZHENG JIANG TEACHERS COLL,ZHENG JIANG,PEOPLES R CHINA
来源：
JOURNAL OF COORDINATION CHEMISTRY | 1997年 / 42卷 / 1-2期
关键词：
heterotrinuclear; cyano bridge; crystal structure; magnetic properties;
D O I：
10.1080/00958979708045280
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A heterotrinuclear complex, (Cutren)(2)Fe(CN)(6).12J(2)O, was synthesised and its crystal structure solved by direct methods. Crystal data are: C18H60N14Cu2FeO12, M = 847.7, monoclinic, space group: P2(1)/c, a = 13.568(5), b = 10.100(3), c = 13.935(6)Angstrom, beta = 95.50(4 degrees, V= 1901(1) Angstrom(3), Z = 2, D-x = 1.48 gcm(-3) final R = 0.039 and R omega = 0.049. The crystal structure shows that the complex is composed of two (Cutren) and one hexacyanometallate Fe(CN)(6) subunits. Bridging cyano C(1)-N(1) is 1.148(4) Angstrom, which is shorter than non-bridging (1.155(4) Angstrom and 1.164(4) Angstrom). Magnetic properties of (Cutren)(2)Fe(CN)(6) indicate weak ferromagnetic exchange over the temperature range of 6.2-37K.
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收藏
页码：55 / 61
页数：7
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