Metal and metal oxide nanoparticles in the voltammetric detection of heavy metals: A review

被引:172
作者
Sawan, Simona [1 ,2 ]
Maalouf, Rita [2 ]
Errachid, Abdelhamid [1 ]
Jaffrezic-Renault, Nicole [1 ]
机构
[1] Univ Lyon, Inst Analyt Sci, 5 Rue Doua, F-69100 Villeurbanne, France
[2] Notre Dame Univ Louaize, Fac Nat & Appl Sci, Dept Sci, Zouk Mosbeh, Lebanon
关键词
Heavy metals; Voltammetry; Metal nanoparticles; Silver nanoparticles; Gold nanoparticles; Bismuth nanoparticles; Metal oxide nanoparticles; Iron oxide nanoparticles; GLASSY-CARBON ELECTRODE; SIMULTANEOUS ELECTROCHEMICAL DETECTION; ANODIC-STRIPPING VOLTAMMETRY; HIGHLY SENSITIVE DETECTION; SCREEN-PRINTED ELECTRODE; GOLD NANOPARTICLES; GRAPHENE OXIDE; MAGNETIC NANOPARTICLES; NANOTUBES COMPOSITES; SELECTIVE DETECTION;
D O I
10.1016/j.trac.2020.116014
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Most heavy metal ions are known to be toxic and carcinogenic when present in high amounts. Thus, rapid and reliable on-site detection of these ions is crucial. Voltammetry is a highly sensitive electrochemical method that has been widely used for heavy metal detection offering the advantages of sensitivity and rapidity. On the other hand, nanoparticles offer the advantages of high surface area and high selectivity. Thus, this review aims to highlight the application of metallic and metallic oxide nanoparticles for the voltammetric detection of heavy metals. The nanoparticles used were either applied solely on the electrode or as modifiers with various materials. In all cases, the synthesized devices showed an enhanced analytical performance, such that the limits of detection were lowered and the sensitivities were increased as compared to voltammetric systems not using nanoparticles. Moreover, the applicability of some of these systems was investigated in real samples. (C) 2020 Elsevier B.V. All rights reserved.
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页数:17
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