Covalent Organic Frameworks and Cage Compounds: Design and Applications of Polymeric and Discrete Organic Scaffolds

被引:424
|
作者
Beuerle, Florian [1 ,2 ,3 ]
Gole, Bappaditya [1 ,2 ,3 ]
机构
[1] Univ Wurzburg, Inst Organ Chem, D-97074 Wurzburg, Germany
[2] CNC, Theodor Boveri Weg, D-97074 Wurzburg, Germany
[3] BPI, Theodor Boveri Weg, D-97074 Wurzburg, Germany
关键词
covalent organic cage compounds; covalent organic frameworks; dynamic covalent chemistry; porous materials; self-assembly; TRIAZINE-BASED FRAMEWORKS; FACE-ROTATING POLYHEDRA; WHITE-LIGHT EMISSION; ORIENTED THIN-FILMS; 3 DIFFERENT KINDS; ONE-POT SYNTHESIS; MOLECULAR CAGES; ROOM-TEMPERATURE; POROUS MATERIALS; RATIONAL DESIGN;
D O I
10.1002/anie.201710190
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Porous organic materials are an emerging class of functional nanostructures with unprecedented properties. Dynamic covalent assembly of small organic building blocks under thermodynamic control is utilized for the intriguingly simple formation of complex molecular architectures in one-pot procedures. In this Review, we aim to analyze the basic design principles that govern the formation of either covalent organic frameworks as crystalline porous polymers or covalent organic cage compounds as shape-persistent molecular objects. Common synthetic procedures and characterization techniques will be discussed as well as more advanced strategies such as postsynthetic modification or self-sorting. When appropriate, comparisons are drawn between polymeric frameworks and discrete organic cages in terms of their underlying properties. Furthermore, we highlight the potential of these materials for applications ranging from gas storage to catalysis and organic electronics.
引用
收藏
页码:4850 / 4878
页数:29
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