Enhanced mechanical properties of radiation vulcanized natural rubber latex by using t-butyl hydroperoxide

被引:4
|
作者
Varghese, Neethu [1 ]
Varghese, Siby [1 ]
Shybi, A. A. [1 ]
Kurian, Thomas [2 ]
机构
[1] Rubber Res Inst India, Tech Consultancy Div, Rubber Board PO, Kottayam 686009, Kerala, India
[2] Cochin Univ Sci & Technol, Dept Polymer Sci & Rubber Technol, Kochi, Kerala, India
关键词
Mechanical properties; FT-IR; kinetics; radiation vulcanization; natural rubber latex;
D O I
10.1177/1477760620977501
中图分类号
TB33 [复合材料];
学科分类号
摘要
The mechanical properties of both radiation (RVNRL) and peroxide vulcanized natural rubber latex (PVNRL) are low when compared to sulphur prevulcanized natural rubber latex (SVNRL). This paper deals with the effect of peroxide on the mechanical properties of radiation vulcanized NR latex film. Here, n-butyl acrylate (n-BA) was used as sensitizer and t-butyl hydroperoxide (t-BHPO) as co-vulcanizing agent during irradiation. It was found that the addition of t-BHPO is more practical method to reduce the vulcanization dose. Thermal ageing study showed that the best retention in tensile properties was shown by RIPV vulcanizates.
引用
收藏
页码:203 / 215
页数:13
相关论文
共 50 条
  • [21] Study on the properties of blend rubber between grafted rubber latex and natural rubber latex by gamma radiation
    Dafader, NC
    Haque, ME
    Akhtar, F
    Ahmad, MU
    POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING, 2006, 45 (07) : 889 - 892
  • [22] DEVELOPMENT OF OPTICAL LASER BALLOON AND DRAINAGE FROM RADIATION VULCANIZED NATURAL-RUBBER LATEX
    SHIMAMURA, Y
    RADIATION PHYSICS AND CHEMISTRY, 1992, 39 (06): : 505 - 507
  • [23] Effect of gamma radiation on physico-mechanical properties of vulcanized natural rubber/carbon fiber composites
    Hassan, Medhat M.
    El-Nemr, Khaled F.
    Abd El-Megeed, Anhar A.
    JOURNAL OF ELASTOMERS AND PLASTICS, 2016, 48 (08): : 677 - 690
  • [24] Effect of montmorillonite modification on mechanical properties of vulcanized natural rubber composites
    Hrachova, Jana
    Komadel, Peter
    Chodak, Ivan
    JOURNAL OF MATERIALS SCIENCE, 2008, 43 (06) : 2012 - 2017
  • [25] Ecofriendly latex films from cassava starch-filled radiation pre-vulcanized natural rubber latex
    Lay, Makara
    Abd Samat, Siti Nuraya
    Hwa, Khor T.
    Rashid, Azura A.
    RADIATION EFFECTS AND DEFECTS IN SOLIDS, 2019, 174 (9-10): : 741 - 751
  • [26] Toughness enhancement of high-impact polystyrene based on γ-radiation vulcanized natural rubber latex by using block copolymer
    Sangribsub, S
    Tangboriboonrat, P
    JOURNAL OF APPLIED POLYMER SCIENCE, 2002, 85 (06) : 1307 - 1316
  • [27] Effect of montmorillonite modification on mechanical properties of vulcanized natural rubber composites
    Jana Hrachová
    Peter Komadel
    Ivan Chodák
    Journal of Materials Science, 2008, 43 : 2012 - 2017
  • [28] Catalytic oxidation of α-pinene by transition metal using t-butyl hydroperoxide and hydrogen peroxide
    Allal, BA
    El Firdoussi, L
    Allaoud, S
    Karim, A
    Castanet, Y
    Mortreux, A
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2003, 200 (1-2) : 177 - 184
  • [29] Study on the properties of blend of natural rubber latex/methyl methacrylate grafted rubber latex by gamma radiation
    Dafader, N. C.
    Haque, M. E.
    Akhtar, F.
    CHINESE JOURNAL OF POLYMER SCIENCE, 2007, 25 (05) : 519 - 523
  • [30] Morphology and mechanical properties of natural rubber and styrene-grafted natural rubber latex compounds
    Arayapranee, Wanvimon
    Rempel, Garry L.
    JOURNAL OF APPLIED POLYMER SCIENCE, 2008, 109 (03) : 1395 - 1402