Highly Efficient lsobutyraldehyde-Mediated Epoxidation of Cyclic Alkenes with Dioxygen Catalyzed by a Novel Dimeric Manganese(II) Complex Containing an Easy-to-Prepare Flexible Carboxamide Ligand

被引：23

作者：

Khavasi, Hamid Reza ^{[1
]}

Sasan, Koroush ^{[1
]}

Pirouzmand, Mahtab ^{[1
]}

Ebrahimi, Samad Nejad ^{[2
]}

机构：

[1] Shahid Beheshti Univ, GC, Dept Chem, Tehran 1983963113, Iran

[2] Shahid Beheshti Univ, GC, Dept Phytochem, Med Plants & Drug Res Inst, Tehran 1983963113, Iran

来源：

INORGANIC CHEMISTRY | 2009年 / 48卷 / 13期

关键词：

MOLECULAR-OXYGEN; OLEFINS; OXIDATIONS; ALDEHYDES;

D O I：

10.1021/ic900334w

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Dioxygen epoxidation of cyclic alkenes into their corresponding epoxides was successfully achieved in good yield by using a novel binuclear manganese carboxamide complex as the catalyst and isobutyraldehyde as the cosubstrate.

引用

页码：5593 / 5595

页数：3

共 27 条

[1] OPTICALLY-ACTIVE LACTONES FROM A BAEYER-VILLIGER-TYPE METAL-CATALYZED OXIDATION WITH MOLECULAR-OXYGEN
BOLM, C
SCHLINGLOFF, G
WEICKHARDT, K
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1994, 33 (18): : 1848 - 1849
[2] EPOXIDATION OF CYCLOHEXENE CATALYZED BY COPPER(II) COMPLEXES UNDER MUKAIYAMAS CONDITIONS
CORAIN, B
TESSARI, A
ZECCA, M
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1995, 96 (01) : L9 - L10
[3] Terpenic olefin epoxidation using metals acetylacetonates as catalysts
Fdil, N
Romane, A
Allaoud, S
Karim, A
Castanet, Y
Mortreux, A
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1996, 108 (01) : 15 - 21
[4] Homogeneous catalysis - Controlled green oxidation
Hill, CL
[J]. NATURE, 1999, 401 (6752) : 436 - 437
[5] CATALYTIC EPOXIDATION WITH MOLECULAR-OXYGEN USING NICKEL-COMPLEX
IRIE, R
ITO, Y
KATSUKI, T
[J]. TETRAHEDRON LETTERS, 1991, 32 (47) : 6891 - 6894
[6] Law NA, 1999, ADV INORG CHEM, V46, P305
[7] MULAIYAMA T, 1993, CHEM LETT, P327
[8] SYNTHETIC ASPECTS OF METAL-CATALYZED OXIDATIONS OF AMINES AND RELATED REACTIONS
MURAHASHI, SI
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (22): : 2443 - 2465
[9] IRON-CATALYZED AND RUTHENIUM-CATALYZED OXIDATIONS OF ALKANES WITH MOLECULAR-OXYGEN IN THE PRESENCE OF ALDEHYDES AND ACIDS
MURAHASHI, SI
ODA, Y
NAOTA, T
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (20) : 7913 - 7914
[10] Nickel complexes as antioxidants. Inhibition of aldehyde autoxidation by nickel(II) tetraazamacrocycles
Nam, W
Baek, SJ
Lee, KA
Ahn, BT
Muller, JG
Burrows, CJ
Valentine, JS
[J]. INORGANIC CHEMISTRY, 1996, 35 (23) : 6632 - &

← 1 2 3 →