Palladium-catalyzed arylation of aryl sulfonamides with cyclohexanones

被引：37

作者：

Cao, Xiangxiang ^{[1
]}

Bai, Yang ^{[1
]}

Xie, Yanjun ^{[1
]}

Deng, Guo-Jun ^{[1
,2
]}

机构：

[1] Xiangtan Univ, Coll Chem, Minist Educ, Key Lab Environm Friendly Chem & Applicat, Xiangtan 411105, Peoples R China

[2] Chinese Acad Sci, Inst Chem, Key Lab Mol Recognit & Funct, Beijing 100080, Peoples R China

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2014年 / 383卷

基金：

高等学校博士学科点专项科研基金; 中国国家自然科学基金;

关键词：

Aromatization; Arylation; Cyclohexanones; Dehydrogenation; Sulfonamides; CROSS-COUPLING REACTIONS; ONE-POT SYNTHESIS; N-ALKYLATION; AEROBIC OXIDATION; MOLECULAR-OXYGEN; AMINE FORMATION; C-N; RUTHENIUM; ALCOHOLS; NITROARENES;

D O I：

10.1016/j.molcata.2013.11.023

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Pd-catalyzed intermolecular aerobic dehydrogenative aromatizations have been developed for the arylation of aryl sulfonamides with cyclohexanones. Various N-aryl sulfonamides were selectively obtained in good yields using molecular oxygen as oxidant. The reaction tolerated a wide range of functionalities. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：94 / 100

页数：7

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