Catalyst excitation by radio frequency for improved carbon nanotubes synthesis

被引:62
作者
Biris, A. R.
Biris, A. S.
Lupu, D.
Trigwell, S.
Dervishi, E.
Rahman, Z.
Marginean, P.
机构
[1] Univ Arkansas, Nanotechnol Ctr, Grad Inst Technol, Little Rock, AR 72204 USA
[2] Natl Inst Res & Dev Isotop & Mol Technol, R-400293 Cluj Napoca, Romania
[3] NASA, Electrostat & Surface Phys Lab, Kennedy Space Ctr, Kennedy Space Ctr, FL 32899 USA
[4] Univ Arkansas, Dept Appl Sci, Little Rock, AR 72204 USA
[5] Univ Cent Florida, Adv Mat Proc & Anal Ctr, Orlando, FL 32826 USA
关键词
LARGE-SCALE; GROWTH; DECOMPOSITION; CCVD;
D O I
10.1016/j.cplett.2006.08.007
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Multiwall carbon nanotubes were grown on Fe:Co:CaCO3 catalysts by catalytic chemical vapor deposition (CCVD) method using two heating methods, external oven and RF inductive heating. Comparative analysis of the nanotubes obtained by the two methods showed that inductive heating generates nanotubes with smaller external diameters, smaller number of walls, an aspect ratio in the range of hundreds, and with a ratio of the outside to the inside diameter ranging between 2 and 2.5. RF heating CCVD is an attractive method for growing carbon nanotubes because of the advantages it presents relative to the enhanced control ability of the growth process. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:204 / 208
页数:5
相关论文
共 23 条
  • [1] ANDO Y, 2004, MATERIALSTODAY 1022
  • [2] Protocol for the characterization of single-wall carbon nanotube material quality
    Arepalli, S
    Nikolaev, P
    Gorelik, O
    Hadjiev, VG
    Bradlev, HA
    Holmes, W
    Files, B
    Yowell, L
    [J]. CARBON, 2004, 42 (8-9) : 1783 - 1791
  • [3] Characterization methods of carbon nanotubes: a review
    Belin, T
    Epron, F
    [J]. MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2005, 119 (02): : 105 - 118
  • [4] CVD synthesis of high-purity multiwalled carbon nanotubes using CaCO3 catalyst support for large-scale production
    Couteau, E
    Hernadi, K
    Seo, JW
    Thiên-Nga, L
    Mikó, C
    Gaál, R
    Forró, L
    [J]. CHEMICAL PHYSICS LETTERS, 2003, 378 (1-2) : 9 - 17
  • [5] Raman spectroscopy on isolated single wall carbon nanotubes
    Dresselhaus, MS
    Dresselhaus, G
    Jorio, A
    Souza, AG
    Saito, R
    [J]. CARBON, 2002, 40 (12) : 2043 - 2061
  • [6] GENNETT T, 2001, MATER RES SOC S P, V633, P1
  • [7] Water-Assisted Highly Efficient Synthesis of Impurity-Free Single-Walled Carbon Nanotubes
    Hata, K
    Futaba, DN
    Mizuno, K
    Namai, T
    Yumura, M
    Iijima, S
    [J]. SCIENCE, 2004, 306 (5700) : 1362 - 1364
  • [8] HELICAL MICROTUBULES OF GRAPHITIC CARBON
    IIJIMA, S
    [J]. NATURE, 1991, 354 (6348) : 56 - 58
  • [9] Long activity of Co-Mo/MgO catalyst for the synthesis of carbon nanotubes in large-scale and application feasibility of the grown tubes
    Kibria, AKMF
    Shajahan, M
    Mo, YH
    Kim, MJ
    Nahm, KS
    [J]. DIAMOND AND RELATED MATERIALS, 2004, 13 (10) : 1865 - 1872
  • [10] Carbon nanotube growth on Ni-particles prepared in situ by reduction of La2NiO4
    Liang, Q
    Gao, LZ
    Li, Q
    Tang, SH
    Liu, BC
    Yu, ZL
    [J]. CARBON, 2001, 39 (06) : 897 - 903