Organic carboxylate ligand directed the structural variation in two Zn(II) coordination polymers

被引：1
|
作者：
Qu, Yingjuan [1 ]
Li, Jing [1 ]
Duan, Shu'e [1 ]
机构：
[1] Xian Univ, Sch Chem Engn, Xian 710065, Shaanxi, Peoples R China
来源：
JOURNAL OF MOLECULAR STRUCTURE | 2018年 / 1166卷
关键词：
Zn(II) compound; Dual-ligand synthetic strategy; Carboxylate ligand; Luminescence; TOPOLOGICAL DIVERSITY; FRAMEWORK SYNTHESES; 3D FRAMEWORK; DESIGN; SERIES; LAYER;
D O I：
10.1016/j.molstruc.2018.04.029
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Two new Zn(II) coordination compounds, namely (Zn-2(mbdc)(2)(bix)(2)ln (1) and Zn-4(bptc)(2)(bix)(4)ln (2) (H(2)mbdc = isophthalic acid, H(4)bptc = biphenyl-3,3',5,5'-tetracarboxylic acid, bix = bis(imidazol-1-ylmethyl)benzene) were successfully obtained using the dual-ligand synthetic strategy. Single crystal X-ray diffraction analyses revealed that compound 1 features a 2-fold interpenetrated 3D dia-type framework, and compound 2 features a trinodal 4-connected 3D topological network. The structural variation was achieved via tuning the organic carboxylate ligand. Moreover, the luminescent properties of compounds 1 and 2 were also investigated in the solid state at room temperature. (C) 2018 Elsevier B.V. All rights reserved.
引用
收藏
页码：155 / 158
页数：4
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