Metastable phase evolution and nanoindentation behavior of amorphous Ni-Cu-P coating during heat treatment process

被引:14
作者
Chen, Jie [1 ]
Zhao, Guanlin [2 ]
Zhang, Yongang [1 ]
Duan, Shuwei [1 ]
Matsuda, Kenji [3 ]
Zou, Yong [1 ]
机构
[1] Shandong Univ, Inst Mat Joining, MOE Key Lab Liquid Solid Struct Evolut & Mat Proc, Jinan 250061, Shandong, Peoples R China
[2] Shandong Univ, Sch Mat Sci & Engn, Jinan 250061, Shandong, Peoples R China
[3] Univ Toyama, Fac Sustainable Design, Dept Mat Design & Engn MaDE, 3190 Gofuku, Toyama, Japan
基金
中国国家自然科学基金;
关键词
Ni-Cu-P amorphous coating; Microstructure evolution; Phase transformation; Nanoindentation; TEM; ELECTROLESS NI; CORROSION-RESISTANCE; CRYSTALLIZATION BEHAVIOR; HIGH-TEMPERATURE; DEPOSITION; HARDNESS; ALLOYS; MICROSTRUCTURE; STABILITY; WEAR;
D O I
10.1016/j.jallcom.2019.07.068
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Effects of heat treatment on the microstructure evolution and phase transition of the Ni-Cu-P amorphous coating, prepared through electroless plating, were investigated by X-ray diffraction (XRD) and transmission electron microscope (TEM). It is found that the metastable Ni5P4, Ni12P5 and Ni5P2 phases were precipitated during the annealing process, which were transformed into stable Ni3P phase after crystallization. Cu atoms in the Ni-Cu-P amorphous coating was precipitated in the form of Ni(Cu) solid solution. Besides, the mechanical properties of the Ni-Cu-P coating during crystallization was systematically studied by nanoindentation measurements. The results showed that the hardness, elastic modulus and wear resistance of the coating were significantly affected by the microstructure evolution and phase transition during the crystallization process. (C) 2019 Elsevier B.V. All rights reserved.
引用
收藏
页码:597 / 608
页数:12
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