Investigation of a Short stack PEM Electrolyzer based on a Nanosized IrO2 Anode Electrocatalyst

被引:0
|
作者
Di Blasi, A. [1 ]
Siracusano, S. [1 ]
Baglio, V. [1 ]
Briguglio, N. [1 ]
Brunaccini, G. [1 ]
Stassi, A. [1 ]
Omelas, R. [2 ]
Antonucci, V. [1 ]
Arico, A. S. [1 ]
机构
[1] CNR, Inst Adv Technol Energy Nicola Giordano, Salita S Lucia Contesse 5, I-98126 Messina, Italy
[2] Tozzi Renewable Energy SpA, I-48010 Mezzano, RA, Italy
来源
CLEAN TECHNOLOGY 2011: BIOENERGY, RENEWABLES, STORAGE, GRID, WASTE AND SUSTAINABILITY | 2011年
关键词
PEM electrolyzer; Stack; Hydrogen production; water electrolysis; IrO2; catalyst; Oxygen evolution reaction;
D O I
暂无
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
A short-stack PEM electrolyzer, consisting of 3 cells of 100 cm(2) geometrical area, was assembled and performed at 75 degrees C under atmospheric pressure. The MEAs were realized by using nanosized IrO2, prepared by a sulfite-complex route, and a Pt/Vulcan X-72 electro-catalysts, as anodic and cathodic electrodes, respectively. After preliminary physico-chemical characterizations (XRD, XRF and TEM) of the IrO2 catalyst, the short-stack performance was investigated by polarization, impedance spectroscopy and chrono-amperometric measurements. The amount of H-2 produced was 80 l.h(-1) 60 A under 330 W of applied electrical power. The stack electrical efficiency at 60 A and 75 degrees C was 70 and 81% with respect to the low and high heating value of hydrogen, respectively.
引用
收藏
页码:181 / 184
页数:4
相关论文
共 50 条
  • [21] Nanostructured F doped IrO2 electro-catalyst powders for PEM based water electrolysis
    Kadakia, Karan Sandeep
    Jampani, Prashanth H.
    Velikokhatnyi, Oleg I.
    Datta, Moni Kanchan
    Park, Sung Kyoo
    Hong, Dae Ho
    Chung, Sung Jae
    Kumta, Prashant N.
    JOURNAL OF POWER SOURCES, 2014, 269 : 855 - 865
  • [22] The role of Nafion content in sputtered IrO2 based anodes for low temperature PEM water electrolysis
    Sapountzi, F. M.
    Divane, S. C.
    Papaioannou, E. I.
    Souentie, S.
    Vayenas, C. G.
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2011, 662 (01) : 116 - 122
  • [23] Fundamental analysis for active phase of rutile-based IrO2 catalyst: Comparison study of CH4 oxidation on IrO2(100) and IrO2(110)
    Kim, Minkyu
    Kang, Sung Bong
    APPLIED SURFACE SCIENCE, 2022, 605
  • [24] Nanosized Pt/IrO2 electrocatalyst prepared by modified polyol method for application as dual function oxygen electrode in unitized regenerative fuel cells
    Cruz, J. C.
    Baglio, V.
    Siracusano, S.
    Ornelas, R.
    Arriaga, L. G.
    Antonucci, V.
    Arico, A. S.
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2012, 37 (07) : 5508 - 5517
  • [25] Investigation of formic acid oxidation on Ti/IrO2 electrodes
    Fierroa, Stephane
    Ouattara, Lassine
    Calderon, Erika Herrera
    Passas-Lagos, Emmanouil
    Baltruschat, Helmut
    Comninellis, Christos
    ELECTROCHIMICA ACTA, 2009, 54 (07) : 2053 - 2061
  • [26] Electrochemical properties of IrO2 active anode with TNTs interlayer for oxygen evolution
    Cao, Huazhen
    Chen, Mengjie
    Wu, Liankui
    Hou, Guangya
    Tang, Yiping
    Zheng, Guoqu
    APPLIED SURFACE SCIENCE, 2018, 428 : 861 - 869
  • [27] TI/IRO2 AS ANODE AND ZR AS CATHODE IN MULTICOMPARTMENT ELECTROLYZERS WITH IMMOBILINE MEMBRANES
    ETTORI, C
    RIGHETTI, PG
    COMNINELLIS, C
    ELECTROPHORESIS, 1992, 13 (1-2) : 55 - 58
  • [28] Electrochemical oxidation of sulfide in oil wastewater using Ti/Iro2 anode
    Wang, Yuting
    Li, Miao
    Feng, Chuanping
    Zhang, Zhenya
    ENVIRONMENTAL PROGRESS & SUSTAINABLE ENERGY, 2012, 31 (04) : 500 - 506
  • [29] A novel highly active nanostructured IrO2/Ti anode for water oxidation
    Shan, Rui
    Zhang, Zichen
    Kan, Miao
    Zhang, Taiyang
    Zan, Qu
    Zhao, Yixin
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2015, 40 (41) : 14279 - 14283
  • [30] IrO2/Nb-TiO2 electrocatalyst for oxygen evolution reaction in acidic medium
    Hu, Wei
    Chen, Shengli
    Xia, Qinghua
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2014, 39 (13) : 6967 - 6976