Tunable giant dielectric properties by Ca doping in Lu1-xCaxFe2O4

被引:3
作者
Wang, Chao [1 ,2 ]
Zhai, Kun [1 ,2 ]
Zhao, Yunchi [1 ,2 ]
Wei, Hongxiang [1 ]
Sun, Young [1 ]
Shen, Shipeng [1 ,3 ]
Cong, Junzhuang [1 ,3 ]
Wang, Shouguo [1 ,3 ]
机构
[1] Chinese Acad Sci, Inst Phys, State Key Lab Magnetism, Beijing 100190, Peoples R China
[2] Univ Chinese Acad Sci, Sch Phys Sci, Beijing 100049, Peoples R China
[3] Beijing Normal Univ, Inst Adv Mat, Beijing 100875, Peoples R China
关键词
Lu1-xCaxFe2O4; Dielectric tunability; Charge ordering; MAGNETIC-PROPERTIES; TUNABILITY; CHARGE; CERAMICS; LUFE2O4; PHASE;
D O I
10.1016/j.jallcom.2018.04.004
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A series of single phase Lu1-xCaxFe2O4 (x= 0, 0.05,0.1) samples were successfully prepared by solid state reaction. The dielectric permittivity/loss at various frequencies and the temperature dependence of the magnetization/resistivity were systematically analyzed. By optimizing Ca-doping, giant dielectric tunability was obtained at low bias electric fields, with great advantages for industrial applications in the near future. Furthermore, the activation energies together with the magnetic moments can be tuned, originating from a variable ratio of Fe2+/Fe3+ by Ca2+ doping. The substitution for Lu3+ by Ca2+ ions provides a novel way to manipulate the dielectric and magnetic properties of charge ordered Lu1-xCaxFe2O4 systems. (C) 2018 Elsevier B.V. All rights reserved.
引用
收藏
页码:333 / 340
页数:8
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