Predictability of 5d level positions of the triply ionized lanthanides in halogenides and chalcogenides

被引:86
作者
Dorenbos, P [1 ]
机构
[1] Delft Univ Technol, Inst Interfac Reactor, NL-2629 JB Delft, Netherlands
关键词
lanthanides; 5d-4f transitions; gaseous Ln(3+); crystal field depression;
D O I
10.1016/S0022-2313(99)00495-0
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Information on 4f-5d transition energies of the triply ionized lanthanides (Ce3+, Pr3+,...,Lu3+) in over 300 different compounds has been gathered, analyzed and occasionally re-interpreted. Some of the main results will be presented. New estimates will be given for the energy of the first electric dipole allowed and some of the spin forbidden fd transitions of the free (gaseous triply ionized lanthanides. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:970 / 972
页数:3
相关论文
共 9 条
[1]   PRASEODYMIUM(III) AS A SENSITIZER OF GADOLINIUM(III) IN YOCL AND GDOCL [J].
BLASSE, G ;
DIRKSEN, GJ ;
VANKOOTEN, WEJ ;
VANWALREE, CA .
CHEMICAL PHYSICS LETTERS, 1988, 146 (3-4) :343-346
[2]   LUMINESCENCE OF PR-3+ IN SCANDIUM BORATE (SCBO3) AND THE HOST LATTICE DEPENDENCE OF THE STOKES SHIFT [J].
BLASSE, G ;
VANVLIET, JPM ;
VERWEY, JWM ;
HOOGENDAM, R ;
WIEGEL, M .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1989, 50 (06) :583-585
[4]  
Brewer L., 1983, SYSTEMATICS PROPERTI, P17
[5]   ON THE POSSIBILITY TO SENSITIZE GD-3+ LUMINESCENCE BY THE PR-3+ ION [J].
DEVRIES, AJ ;
BLASSE, G .
MATERIALS RESEARCH BULLETIN, 1986, 21 (06) :683-694
[6]  
Lang R.J., 1936, Canadian Journal of Research, V14a, P127
[7]   ELECTRON-TRANSFER AND F-D ABSORPTION-BANDS OF SOME LANTHANIDE AND ACTINIDE COMPLEXES AND STANDARD (II-III) OXIDATION POTENTIAL FOR EACH MEMBER OF LANTHANIDE AND ACTINIDE SERIES [J].
NUGENT, LJ ;
BAYBARZ, RD ;
BURNETT, JL ;
RYAN, JL .
JOURNAL OF PHYSICAL CHEMISTRY, 1973, 77 (12) :1528-1539
[8]   IONIZATION ENERGIES OF DOUBLY AND TRIPLY IONIZED RARE-EARTHS [J].
SUGAR, J ;
READER, J .
JOURNAL OF CHEMICAL PHYSICS, 1973, 59 (04) :2083-2089