Vibrational relaxation of H2 in collisions with rotationally excited H2 molecules

被引：15
|
作者：
Flower, DR [1 ]
机构：
[1] Univ Durham, Dept Phys, Durham DH1 3LE, England
来源：
JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS | 2000年 / 33卷 / 05期
关键词：
D O I：
10.1088/0953-4075/33/5/107
中图分类号：
O43 [光学];
学科分类号：
070207 ; 0803 ;
摘要：
We have investigated the influence of rotational excitation of the perturber molecule on the rate coefficient for vibrational relaxation of para-Hz. Comparison is made with our previous (quantum mechanical) calculations, which assumed the perturber molecule to be constrained to its rotational ground state, and with measurements of the rate coefficient. We also compare with the results of recent semi-classical calculations by Zenevich and Billing (Zenevich V A and Billing G D 1999 J. Chem. Phys. 111 2401).
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收藏
页码：L193 / L195
页数：3
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