Facile and cost effective synthesis of mesoporous spinel NiCo2O4 as an anode for high lithium storage capacity

被引:122
作者
Jadhav, Harsharaj S. [1 ]
Kalubarme, Ramchandra S. [1 ]
Park, Choong-Nyeon [1 ]
Kim, Jaekook [1 ]
Park, Chan-Jin [1 ]
机构
[1] Chonnam Natl Univ, Dept Mat Sci & Engn, Kwangju 500757, South Korea
基金
新加坡国家研究基金会;
关键词
CATHODE MATERIALS; NANOWIRE ARRAYS; ION BATTERIES; METAL-OXIDE; PERFORMANCE; CO3O4; MICROSPHERES; NANOTUBES; MECHANISM;
D O I
10.1039/c4nr02183e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
To fulfill the high power and high energy density demands for Li-ion batteries (LIBs) new anode materials need to be explored to replace conventional graphite. Herein, we report the urea assisted facile co-precipitation synthesis of spinel NiCo2O4 and its application as an anode material for LIBs. The synthesized NiCo2O4 exhibited an urchin-like microstructure and polycrystalline and mesoporous nature. In addition, the mesoporous NiCo2O4 electrode exhibited an initial discharge capacity of 1095 mA h g(-1) and maintained a reversible capacity of 1000 mA h g(-1) for 400 cycles at 0.5 degrees C-rate. The reversible capacity of NiCo2O4 could still be maintained at 718 mA h g(-1), even at 10 degrees C. The mesoporous NiCo2O4 exhibits great potential as an anode material for LIBs with the advantages of unique performance and facile preparation.
引用
收藏
页码:10071 / 10076
页数:6
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