Hydrothermal Synthesis and Crystal Structure of a Complex with Pyrogallic Acid and N-donor Ligand: 2-(4-methoxyphenyl)-1H-imidazo[4,5-f][1,10] Phenanthroline

被引：1
作者：
Huang, Yan-Ju [1 ]
Yan, Yong-Sheng [2 ]
Du, Gang [3 ]
Liang, Yue [1 ]
机构：
[1] Tonghua Normal Univ, Dept Chem, Tonghua 134002, Peoples R China
[2] Jiangsu Univ, Sch Chem & Chem Engn, Zhenjiang, Peoples R China
[3] Tonghuas 1 Middle Sch, Tonghua, Peoples R China
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2014年 / 44卷 / 10期
关键词：
complex; crystal structure; hydrothermal synthesis; POLYMERS;
D O I：
10.1080/15533174.2013.817422
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The complex [Ni(MOPIP)(3)(C6H5O3)](n)center dot nH(2)O 1 (C6H5O3 = pyrogallic acid, MOPIP = 2-(4-methoxyphenyl)-1H-imidazo[4,5-f][1,10] phenanthroline) has been hydrothermally synthesized and structurally characterized by elemental analysis, IR spectrum, TG, and single-crystal X-ray diffraction. Complex 1 crystallizes in the monoclinic system, space group P 21/c, with a = 17.249 (3), b = 15.014 (3), c = 21.437 (4) angstrom, = 92.14 (3), V = 5547.7 (19) angstrom(3), and Z = 4 [at 293 (2) K]. In the crystal structure, the nickel atom is six coordinated with six nitrogen atoms from MOPIP ligand, showing a slightly distorted octahedral geometry. Furthermore, it exhibits a zero-dimensional (0D) structure with Ni-MOPIP as building units. The complex 1 extends 3D supramolecular structure through the hydrogen bonds and the - stacking interactions enhance the stability of the complex.
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页码：1483 / 1486
页数：4
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