Effect of amylose/amylopectin content and succinylation on properties of corn starch nanoparticles as encapsulants of anthocyanins

被引：63

作者：

Escobar-Puentes, Alberto A. ^{[1
]}

Garcia-Gurrola, Adriana ^{[1
]}

Rincon, Susana ^{[2
]}

Zepeda, Alejandro ^{[3
]}

Martinez-Bustos, Fernando ^{[4
]}

机构：

[1] Univ Autonoma Ciudad Juarez, Inst Ciencias Biomed, Anillo Envolvente Pronaf & Estocolmo S-N, Cd Juarez Rez 32310, Chihuahua, Mexico

[2] Tecnol Nacl Mexico IT Merida, Dept Posgrad, Ave Tecnol Km 4-5 S-N, Merida 97118, Yucatan, Mexico

[3] Univ Autonoma Yucatan, Fac Ingn Quim, Campus Ciencias Exactas & Ingn, Merida 97203, Yucatan, Mexico

[4] Inst Politecn Nacl, Ctr Invest & Estudios Avanzados, Dept Nanomat, Unidad Queretaro, Libramiento Norponiente 2000, Queretaro 76230, Queretaro, Mexico

来源：

CARBOHYDRATE POLYMERS | 2020年 / 250卷

关键词：

Anthocyanins; Amylose/amylopectin; Starch nanoparticles; Nanoencapsulation; Succinylation; AMYLOSE; EXTRUSION; COMPLEXES; CHITOSAN; GELATIN; SULFATE;

D O I：

10.1016/j.carbpol.2020.116972

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

In this study, succinylated nanoparticles from normal (NPS-N), high-amylose (NPS-H), and high-amylopectin corn starch (NPS-W) were synthesized, characterized, and studied for the nanoencapsulation of the Ardisia compressa anthocyanins. The nanoparticle-anthocyanin interaction was also investigated. The succinylated starch nanoparticles (S-SNPs) had hydrodynamic sizes of 65-390 nm, degrees of substitution (DS) of 0.014-0.032, zeta-potential values of up to -34 mV and a nanocolloid behavior. NPS-N and NPS-W showed the highest (p < 0.05) encapsulation efficiencies (EE) (52 and 49 %, respectively) compared than NPS-H (45 %). Thereby, the lowest DS obtained, and the branched amylopectin structure favored the EE. The nanoparticle-anthocyanin interaction occurred through hydrophobic and electrostatic interactions and influenced significantly (p < 0.05) the hydrodynamic size and surface properties of the resulting nanocapsules. The relative crystallinity (RC) decreased significantly (p < 0.05) in the S-SNPs, but the nanocapsules mostly experimented a structural recrystallization and showed melting temperatures >150 degrees C.

引用

页数：10

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