Synthesis and x-ray crystal structure of [1,3-bis(eta(5)-cyclopentadienyl)-1,1,3,3-tetramethyldisiloxane]hafnium(IV) dichloride

被引：0

作者：

Klouras, N

Tzavellas, N

Raptopoulou, CP

机构：

[1] UNIV PATRAS,DEPT CHEM,GR-26500 PATRAS,GREECE

[2] NRCPS DEMOKRITOS,INST MAT SCI,GR-15310 ATHENS,GREECE

来源：

MONATSHEFTE FUR CHEMIE | 1997年 / 128卷 / 10期

关键词：

hafnium; cyclopentadienyl; ansa-metallocenes; X-ray analysis;

D O I：

10.1007/BF00806962

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The tetramethyldisiloxane-bridged hafnocene complex [HfCl2{mu-(eta(5)-C5H4)SiMe2OSiMe2(eta(2)-C5H4)}] (1) has been prepared by the reaction of HfCl4 with the dilithiated bis(cyclopentadienyl)disiloxane (LiC5H4SiMe2)(2)O in a molar ratio of 1:2. The new compound was characterized by spectroscopic and X-ray diffraction methods. The crystals are monoclinic of space group P2(1)/c and isostructural with the corresponding complexes of titanium and zirconium. The unit cell dimensions are a = 13.51(1)Angstrom, b = 8.672(7)Angstrom, c = 15.41(1) Angstrom, beta = 97.15(2)degrees, and Z = 4.

引用

页码：961 / 967

页数：7

共 50 条

[1] Synthesis and X-ray crystal structure of [1,3-bis(η5-cyclopentadienyl)-1,1,3,3-tetramethyldisiloxane]hafnium(IV) dichlorideDarstellung und Röntgenkristallstruktur von [1,3-Bis(η5-cyclopentadienyl)-1,1,3,3-tetramethyldisiloxan]hafnium(IV)dichlorid
N. Klouras
N. Tzavellas
C. P. Raptopoulou
Monatshefte für Chemie / Chemical Monthly, 1997, 128 (10) : 961 - 967
[2] SYNTHESIS OF TITANOCENE DERIVATIVES OF TETRAMETHYLDISILOXANE AND POLY(METHYLSILOXANE) AND THE MOLECULAR-STRUCTURE OF THE DISILOXANE-BRIDGED TITANOCENE DICHLORIDE (1,3-BIS(ETA-5-CYCLOPENTADIENYL)-1,1,3,3-TETRAMETHYLDISILOXANE)-TITANIUM(IV) DICHLORIDE
CURTIS, MD
DERRICO, JJ
DUFFY, DN
EPSTEIN, PS
BELL, LG
ORGANOMETALLICS, 1983, 2 (12) : 1808 - 1814
[3] 1,3-BIS(2-BENZOYLPHENYL)-1,1,3,3-TETRAMETHYLDISILOXANE
WIESE, D
WANNAGAT, U
THEWALT, U
DEBAERDEMAEKER, T
CHEMISCHE BERICHTE-RECUEIL, 1987, 120 (06): : 873 - 878
[4] Synthesis and X-ray crystal structure of bis[eta(5)-1,3-bis(trimethylsilyl)cyclopentadienyl] lanthanide and yttrium iodide complexes
Xie, ZW
Liu, ZX
Xue, F
Zhang, ZY
Mak, TCW
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1997, 542 (02) : 285 - 289
[5] Synthesis and characterization of new polyamides containing 1,3-bis(p-carboxyphenyl)-1,1,3,3-tetramethyldisiloxane
Lee, SM
Kim, KS
Park, KT
POLYMER-KOREA, 1996, 20 (01) : 25 - 32
[6] Synthesis of {1,3-bis(η5-tetramethylcyclopentadienyl)-1,1,3,3-tetramethyldisiloxane}dichlorotitanium(IV) via hydrolysis of bis{η5-(N,N-dimethylaminodimethylsilyl) tetramethylcyclopentadienyl}dichlorotitanium(IV)
Zemánek, J
Horácek, M
Thewalt, U
Stepnicka, P
Kubista, J
Cejka, J
Petrusová, L
Mach, K
INORGANIC CHEMISTRY COMMUNICATIONS, 2001, 4 (09) : 520 - 525
[7] Complexation of phosphates by 1,3-bis(3-(2-pyridylureido)propyl)-1,1,3,3-tetramethyldisiloxane
Franski, Rafal
Gierczyk, Blazej
Markiewicz, Grzegorz
Kozik, Tomasz
RAPID COMMUNICATIONS IN MASS SPECTROMETRY, 2015, 29 (23) : 2272 - 2278
[8] Chemical properties of 1,3-bis(3-methacryloxypropyl)-1,1,3,3-tetramethyldisiloxane - methyl methacrylate copolymer
Aoyagi, Yujin
Umemoto, Kozo
Kurata, Shigeaki
DENTAL MATERIALS JOURNAL, 2012, 31 (02) : 215 - 218
[9] Monolayers of 1,3-bis(10-carboxydecanyl)-1,1,3,3-tetramethyldisiloxane at the water-air interface
Rudoy, VM
Fedotov, NS
Chasovnikova, LV
COLLOID JOURNAL, 1996, 58 (05) : 632 - 635
[10] Mechanism of formation of macrocyclic siloxanes with a benzimidazole fragment by reaction of benzimidazole with 1,3-bis(iodomethyl)-1,1,3,3-tetramethyldisiloxane
Shagun, V. A.
Zhilitskaya, L. V.
Shagun, L. G.
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2016, 52 (07) : 1000 - 1006

← 1 2 3 4 5 →