Synthesis, magnetic behavior and structural characterization of novel one-dimensional copper(II) coordination polymer based on azide and oxalate bridges

被引：7

作者：

Switlicka-Olszewska, A. ^{[1
]}

Machura, B. ^{[1
]}

Mrozinski, J. ^{[2
]}

机构：

[1] Silesian Univ, Inst Chem, Dept Crystallog, PL-40006 Katowice, Poland

[2] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2014年 / 43卷

关键词：

Coordination polymer; Copper(II); Oxalate; Azide; X-ray; Magnetic measurements; CRYSTAL-STRUCTURE; COMPLEXES; LIGANDS; CARBOXYLATE; COMPOUND;

D O I：

10.1016/j.inoche.2014.02.013

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel compound [Cu-2(mu(1.1)-N-3)(2)(C2O4)(bpzm)(2)](n) incorporating simultaneously azide and oxalate bridges has been synthesized and characterized in the context of its structural and magnetic properties. The crystal structure has been determined by single-crystal X-ray analysis. Additionally, the compound was characterized using IR, UV-vis and thermal analyses. The investigated complex [Cu-2(mu(1.1)-N-3)(2)(C2O4)(bpzm)(2)](n) represents an interesting magnetic system of Cu(II) centers with alternating ferro- and antiferromagnetic coupling. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：86 / 89

页数：4

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