Towards enzyme-like enantioselectivity in the gas phase: conformational control of selectivity in chiral macrocyclic dimers

被引：7

作者：

Fraschetti, Caterina ^{[1
]}

Pierini, Marco ^{[1
]}

Villani, Claudio ^{[1
]}

Gasparrini, Francesco ^{[1
]}

Mortera, Stefano Levi ^{[1
]}

Speranza, Maurizio ^{[1
]}

机构：

[1] Univ Roma La Sapienza, Dipartimento Chim & Tecnol Farmaco, Rome, Italy

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 36期

关键词：

D O I：

10.1039/b909017g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Conformational factors in self-assembled chiral tetraamide macrocycles control their gas-phase enantioselectivity towards the ethyl ester of naphthylalanine to levels typical of enzymes.

引用

页码：5430 / 5432

页数：3

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