Composition, properties, and electrochemical behavior of nonstoichiometric manganese dioxide obtained in fluoride-containing electrolytes

被引：5
|
作者：
Ivanova, ND
Boldyrev, E
Sokol'skii, GV
Makeeva, IS
机构：
[1] Natl Acad Sci Ukraine, Inst Gen & Inorgan Chem, UA-252142 Kiev, Ukraine
[2] Natl Aviat Univ, Kiev, Ukraine
来源：
RUSSIAN JOURNAL OF ELECTROCHEMISTRY | 2002年 / 38卷 / 09期
关键词：
D O I：
10.1023/A:1020288927771
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
The composition, properties, and structure of manganese dioxide samples are studied. Deviation of the compound composition from stoichiometry affects the ionic component of the conductivity as well as catalytic and electrochemical activities of the compound. The higher the MnO2 deviation from stoichiometry, the better the electric parameters of prototype batteries with cathodes based on MnO2.
引用
收藏
页码：981 / 986
页数：6
相关论文
共 50 条
  • [41] Anodic oxidation of titanium in fluoride-containing electrolytes based on ethylene glycol and dimethyl sulfoxide
    L. N. Inasaridze
    A. V. Balmasov
    Protection of Metals and Physical Chemistry of Surfaces, 2015, 51 : 523 - 526
  • [42] pH dependent passivation behavior of niobium in acid fluoride-containing solutions
    Guan, Lei
    Li, Yu
    Wang, Guan
    Zhang, Yongkang
    Zhang, Lai-Chang
    ELECTROCHIMICA ACTA, 2018, 285 : 172 - 184
  • [43] Electrochemical behavior of manganese dioxide on a gold electrode
    Rogulski, Z
    Siwek, H
    Paleska, I
    Czerwinski, A
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2003, 543 (02): : 175 - 185
  • [44] Antibacterial surface properties of fluoride-containing resin-based sealants
    Naorungroj, Supawadee
    Wei, Hong-Hong
    Arnold, Roland R.
    Swift, Edward J., Jr.
    Walter, Ricardo
    JOURNAL OF DENTISTRY, 2010, 38 (05) : 387 - 391
  • [45] SURFACE-ACTIVE PROPERTIES OF FLUORIDE-CONTAINING ESTERS OF ACRYLIC ACIDS
    BEKHLI, LS
    LYAPUNOV, AY
    MARKEVICH, AM
    ZHURNAL FIZICHESKOI KHIMII, 1982, 56 (11): : 2898 - 2900
  • [46] Cobalt Additives Influence on Phase Composition and Defect Structure of Manganese Dioxide Prepared from Fluorine Containing Electrolytes
    Sokolsky, G. V.
    Ivanov, S. V.
    Ivanova, N. D.
    Boldurev, Ye. I.
    Kobulinskaya, O. V.
    Demchenko, M. V.
    ACTA PHYSICA POLONICA A, 2010, 117 (01) : 86 - 90
  • [47] Effects of Thermal Treatment on the Electrochemical Behavior of Manganese Dioxide
    Mi Juan
    Wang Yu-Ting
    Gao Peng-Cheng
    Li Wen-Cui
    ACTA PHYSICO-CHIMICA SINICA, 2011, 27 (04) : 893 - 899
  • [48] Electrochemical behavior of manganese in chloride-bromide-ammonium electrolytes
    L. F. Kozin
    N. V. Mashkova
    F. D. Manilevich
    B. I. Danil’tsev
    Russian Journal of Applied Chemistry, 2007, 80 : 730 - 733
  • [49] Electrochemical behavior of manganese in chloride-bromide-ammonium electrolytes
    Kozin, L. F.
    Mashkova, N. V.
    Manilevich, F. D.
    Danil'tsev, B. I.
    RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2007, 80 (05) : 730 - 733
  • [50] Electrochemical behavior of manganese in chloride-bromide-ammonium electrolytes
    Kozin, L.F.
    Mashkova, N.V.
    Manilevich, F.D.
    Danil'tsev, B.I.
    Russian Journal of Applied Chemistry, 2007, 80 (05): : 730 - 733
12345