Facile synthesis of carbon-ZnO nanocomposite with enhanced visible light photocatalytic performance

被引:71
作者
Akir, Sana [1 ,2 ,3 ]
Hamdi, Abderrahmane [1 ,2 ,4 ]
Addad, Ahmed [5 ]
Coffinier, Yannick [1 ]
Boukherroub, Rabah [1 ]
Omrani, Amel Dakhlaoui [3 ,6 ]
机构
[1] Univ Lille, Univ Valenciennes, CNRS, ISEN,Cent Lille,UMR 8520,IEMN, F-59000 Cent Lille, France
[2] Univ Carthage, Fac Sci Bizerte, Lab Phys Mat Lamellaires & Nanomat Hybrides, Bizerte 7021, Tunisia
[3] Ctr Natl Rech Sci Mat, Lab Physicochim Mat Mineraux & Leurs Applicat, Technopole Bordj Cedria,BP73, Soliman 8027, Tunisia
[4] Res & Technol Ctr Energy, Lab Semicond Nanostruct & Adv Technol, Borj Cedria Sci & Technol Pk,BP 95, Hammam Lif 2050, Tunisia
[5] Univ Lille 1, UMR CNRS 8207, UMET, F-59655 Villeneuve Dascq, France
[6] Univ Jeddah, Fac Sci & Arts Khulais, Dept Chem, POB 355, Jeddah 21921, Saudi Arabia
关键词
C-ZnO nanocomposite; Stability; Rhodamine B; Photocatalysis; Visible light; REDUCED GRAPHENE OXIDE; RAMAN-SPECTROSCOPY; DEGRADATION; COMPOSITES; NANOPARTICLES; ROUTE; PHOTODEGRADATION; PHOTOSTABILITY; NANOSTRUCTURES; NANOCRYSTALS;
D O I
10.1016/j.apsusc.2016.12.212
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The present study describes a facile route for synthesis of carbon-ZnO nanocomposites (C-ZnO) via hydrothermal process in presence of glucose as carbon precursor. The samples were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDX), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), UV vis diffuse reflectance spectroscopy (DRS) and photoluminescence (PL) measurements. The results showed carbon uniformly coated on the surface of the ZnO nanoparticles to form the C-ZnO nanocomposites. Further investigation revealed that carbon could significantly protect ZnO NPs against the coalescence during high temperature treatment. The obtained C-ZnO nanocomposite showed excellent photocatalytic activity for the degradation of rhodamine B (RhB) under visible light irradiation, which was attributed to the repressed charge carrier recombination in the nanocomposite. Quenching experiments and photocurrent measurements revealed a photocatalytic mechanism occurring through photosensitization. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:461 / 470
页数:10
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